毕业设计—年产40万吨ABS树脂的工艺设计.docxVIP

年产40万吨ABS树脂HRG单元聚合工艺设计 摘 要 ABS树脂为丙烯腈A（acrylonitrile）、丁二烯B（butadiene）和苯乙烯S（styrene）三种单体共聚而成的聚合物，简称ABS。ABS树脂的刚性、耐磨性以及耐热性均比较强，并且无毒、无味，尺寸结构稳定，因此，在汽车工业、电子工业、建筑行业中均得到推广和应用。 本文首先介绍了ABS树脂的基本结构、理化性质及其应用领域，然后查阅资料，对ABS树脂的生产工艺进行调研，分析国内外ABS树脂生产技术情况，阐述了当前生产ABS树脂的主要生产工艺，即乳液接枝-本体SAN掺混法。本文重点介绍了HRG单元聚合反应的工艺路线，针对物料衡算、热能衡算及反应釜、搅拌器和中间产品储罐等工艺设备进行设计计算，同时对“三废”的后期处理给出了建议。针对目前工艺中存在的问题和不足，通过查阅资料，并结合实际生产情况，提出合理化的建议。 关键词： ABS树脂 聚合工序 反应釜 Design of ABS resin HRG unit polymerization process with annual output of 400,000 tons ABSTRACT ABS resin is a copolymer of acrylonitrile a (acrylonitrile), butadiene B (butadiene) and styrene s (styrene). ABS resin has strong rigidity, wear resistance and heat resistance, and is non-toxic, tasteless and stable in size and structure. Therefore, it has been promoted and applied in automobile industry, electronic industry and construction industry. In this paper, the basic structure, physical and chemical properties and application fields of ABS resin are introduced. Then, the production technology of ABS resin is investigated, the production technology of ABS resin at home and abroad is analyzed, and the main production process of ABS resin is described, namely, emulsion grafting and bulk SAN blending. This paper mainly introduces the process route of HRG unit polymerization reaction, designs and calculates the material balance, heat balance, reactor, agitator, intermediate product storage tank and other process equipment, and gives suggestions on the post-treatment of three wastes. In view of the problems and deficiencies existing in the current process, through consulting the data and combining with the actual production situation, reasonable suggestions are put forward. Key Words: ABS Resin Aggregation Process Reaction Kettle PAGE PAGE 37 目录 TOC \o 1-3 \h \u 第一章 ABS树脂的介绍 3 1.1 ABS树脂的结构与性质 3 1.2 ABS树脂的合成工艺 4 1. 乳液接枝掺混法 4 2. 连续本体法 4 1.3 ABS树脂的应用 4 1.3.1 ABS树脂在汽车工业上的应用 4 1.3.2 ABS树脂在生活中的应用 4 第二章 设计项目简介 5 2.1 设计项目名称