碱性亚硫酸盐法脱木素工艺参数对巴沙木性能影响的研究_王鲁浩.pdfVIP

林产工业 2020 57 08 9-14 ， ， （ ）： China Forest Products Industry 碱性亚硫酸盐法脱木素工艺参数对巴沙木性能影响的研究∗ 王鲁浩  张  健  李  黎  罗  斌  刘红光  （北京林业大学材料科学与技术学院，北京  100083） 摘要：  脱木素处理是开发功能性木质复合材料常用的工艺方法，木质素的去除改变了处理材的物理力学性能，进而对 制备的复合材料产生影响。研究考查了碱性亚硫酸盐法脱除巴沙木木质素过程中，溶液浓度和处理时间对巴沙木质量 损失、接触角、色差以及比表面积的影响。通过建立工艺参数与处理材物理力学性能之间关系，为功能性木质复合材料 的预处理工艺提供理论依据。结果表明：相比未处理材，脱木素处理材质量损失率随溶液浓度和处理时间的增加而增 加；颜色偏向明亮黄绿色，颜色变化与工艺参数没有显著关系；处理材亲水性显著提高，与工艺参数无关；处理材的宏观 比表面积与未处理材相比略有降低。 关键词：  木质素脱除； 碱性亚硫酸盐； 木质复合材料； 比表面积； 色差 TS65 A 中图分类号： 文献标识码： 文章编号：1001-5299 （2020） 08-0009-06 DOI:10.19531/j.issn1001-5299.202008003 Study on the Effect of Alkaline Sulfite Delignification Process Parameters on the Properties of Ochromalagopus WANG Lu-hao ZHANG Jian LI Li LUO Bin LIU Hong-guang ( College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, P.R.China ) Abstract: The process of delignification was usually used in fabrication of functionalized wood composites, which changed the physical and mechanical properties of lignin-removed wood, and then, at some extent, affected the comprehensive performance of wood composites in the end. In this paper, the mass loss, surface contact angle, color difference and specific surface area were studied in the process of alkaline sulfite delignification under different solution concentration and processing time. The change rule between the process parameters and the physical and mechanical properties of lignin-removed wood was verified, which provided theoretical foundations for the fabrication of functionalized wood composites. Compared with untreated wood, the mass loss ratio of treated wood increased with the growth of solution conc