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Bond dissociation energies Yu-ran Luo The bond dissociation energy (enthalpy) is also referred to as (1) Table 1: Bond Dissociation Energies in Diatomic bond disruption energy, bond energy, bond strength, or binding Molecules energy (abbreviation: BDE, BE, or D) . It is defined as the standard (2) Table 2: Enthalpy of Formation of Gaseous Atoms enthalpy change of the following fission: R−X → R + X . The BDE, (3) Table 3: Bond Dissociation Energies in Polyatomic denoted by Do (R−X), is usually derived by the thermochemical Molecules equation, Do o o o (R−X) = ∆H (R) + ∆H (X) – ∆H (RX) . The enthalpy (4) Table 4: Enthalpies of Formation of Free Radicals and f f f o of formation ∆H of a large number of atoms, free radicals, ions, Other Transient Species f clusters and compounds is available from the websites of NIST, (5) Table 5: Bond Dissociation Energies of Common Organic NASA, CODATA, and IUPAC . Most authors prefer to use the Molecules BDE values at 298 .15 K . (6) Table 6: Bond