年产20万吨环氧丙烷精制工段设计2021年最新版.docxVIP

年产 20 万吨环氧丙烷精制工段的设计 摘 要 3 6本设计中以丙烯，甲醇以及双氧水为原料，合成浓度为 99.7%的环氧丙烷（PO）。其工艺流程是：用甲醇溶解原料 C H ，通过萃取精馏和普通精馏两个塔的联用得到优等品（质量分数≥99.7%） 3 6 设计首先对生产流程进行了科学合理的物料衡算与热量衡算，同时采用Aspen Plus 对精馏塔和换热器进行模拟；并对生产设备如精馏塔、换热器设备等重要设备进行了设计，其中精馏段的工艺设计包括：精馏塔的物料衡算、塔板数的确定、物性估算、塔体工艺尺寸设计、流体力学验算、精馏塔的热量衡算与塔附件的设计；换热器的设计包括：换热器的选型，换热器工艺设计，压力强度的校核，最后对工艺的三废处理和经济效益进行了分析。 关键词：环氧丙烷; 换热器; 工艺设计 I 年产 年产 20 万吨环氧丙烷精制工段的设计 滨州学院学士学位设计 滨州学院学士学位设计 2 2 3 3 Design of Epoxy Propane Refining Section with Annual Output of 200000 Tons Abstract 3 6In this design, propylene oxide (PO) with 99.7% purity was produced, using methanol and hydrogen peroxide as raw material. The production process flow was as followed. Firstly, materials C H was dissolved by methanol. Then an excellent products (mass fraction more than 99.7%) of the 3 6 The whole process design included the material balance, heat balance of the production process. Meanwhile, rectification tower and heat exchanger were simulated using Aspen Plus. Furthermore, the important production equipment, such as distillation tower and heat exchanger were designed. The distillation tower of the process design include: material balance calculation, determination of the number of plates, estimation of properties, dimension of tower body design and calculation of fluid mechanics. The design of heat exchanger comprised with selecting and designing of the heat exchanger. The stress intensity was also checked. Finally, the three waste treatment and economic benefit of the process are analyzed. Keywords: Propylene oxide; Heat exchanger; Process design 目 录 引言 7 综述 8 环氧丙烷的性质及应用 8 环氧丙烷的性质 8 环氧丙烷的应用 8 环氧丙烷的市场生产情况 8 设计依据 8 原料的选择及工艺参数的选择 9 换热器 9 工艺设计与计算 10 工艺原理 10 工艺路线的选择 10 丙烷脱氢制丙烯工艺 10 丙烯生产环氧丙烷（PO）工艺 11 工艺流程的确定 14 丙烷脱氢车间流程模拟 19 丙烷脱氢反应、预分离工段模拟 19 压缩、深冷分离工段模拟 19 丙烯提纯分离工段模拟 20 环氧化车间流程模拟 20 PO 分离、精制工段模拟 21 萃取剂回收工段模拟 21 丙二醇分离、精制工段模拟 22 物料衡算 22 物料衡算基本原理 22 精馏塔的物料平衡 23 能量衡算 24 年产 年产 20 万吨环氧丙烷精制工段的设计 滨州学院学士学位设计 滨州学院学士学位设计 PAGE PAGE 4 PAGE PAGE 5 基本原理 24 冷凝剂 25 焓值衡算 25 设备设计计算 28 设计原则