课件参考文稿28-chapter27.pptxVIP

Chapter 27 Chemical kinetics (2);Motivation Question:;1. Basic ideas ;2. Rate equation;;Collision theory clarifies the significance of A and E in Arrhenius equation.It can calculate Z, A and k using a molecular diameter and weight.But activation energy needs determining by experiment. ;3. Bimolecular collision frequency;;This is the frequency when one moving molecule A collides with NB/V moving molecules B, in which μr is the relative speed of A to B instead of the average speed μA. If A and B are in the same direction, μr=μA-μB.  If A and B are in the opposite direction, μr=μA+μB.  If A and B are in the vertical direction, ;;;Comprehension Question:;4. Threshold energy of reaction;27-2 Transition state theory (Absolute rate theory);2. Rate equation;;3. Calculation on K≠ ;;;4. Potential energy surface;;Comprehension Question:;27-3 Unimolecular reaction theory;2. Rate equation;3. Explanation for experiment;Discussion Question:;Homework