高分子结晶上.pptxVIP

Extensions of the Avrami Equation to Various Polymer Crystallization Models JAMES N. HAY* and ZBIGNIEW J. PRZEKOP Department of Chemistry, The University of Birmingham, Birmingham B15 2TT, England J. Polym. Sci., Polym. Phys. Ed., 1979, 17(6), 951-9 ;Computer modelling studies of the progress of crystallization in polymer melts mixed mechanism, volume shrinkage variable crystalline density nonrandom nucleation. It is concluded that the Avrami equation is a reasonable approximation to most of these systems except (c). ;第3页/共20页;第4页/共20页;第5页/共20页;第6页/共20页;Clearly, the computer simulation of polymer crystallization as described above is potentially a powerful technique for assessing models. As used above, it had its limitations, as the number of scanning points adopted was restricted by the computational time, but with faster and more powerful computers this technique will become more accurate and more successful. ;Galeski (1981) simulated two-dimensional and three-dimensional spherulite growth and showed the Avrami exponent, the spherulite size distributions and morphology for different nucleation modes.;第9页/共20页;第10页/共20页;第11页/共20页;第12页/共20页;第13页/共20页;Computer simulation showed that the type of primary nucleation influences not only the Avrami exponent but also the spherulite size distribution. ;E. Pineda, T.Pradell, et al. (2001);第16页/共20页;第17页/共20页;第18页/共20页;第19页/共20页;感谢您的观看！