《综合分析举例》.ppt

《材料研究方法》研究生课程 浙江工业大学 化工与材料学院 材料系 第10章 综合分析举例 Li-Ping Yang, Cai-Yuan Pan, Macromol. Chem. Phys. 2008, 209, 783-793 1 Six-armed star Poly(L-lactic acid) MWNT PLLA-MWNT Figure 1 Typical 1H NMR spectra of A) PLLA2 and B) MWCNT-PLLA2 composites Figure 2. FT-IR spectra of A) pristine MWCNTs, B) PLLA2, and C) MWCNT-PLLA2 composites. Figure 3. Typical UV-vis absorption spectra of A) PLLA2 and B) MWCNT-PLLA2 composites. The inset figure shows the variation of absorption intensity of the MWCNT-PLLA2 suspension at300–800 nm with time. Figure 4. Fluorescence spectra of A) PLLA2 and B) MWCNT-PLLA2 composites. Figure 5. Raman spectra of A) the MWCNT-PLLA2, B) the pristine MWCNTs, C) the MWCNTs obtained after alkaline hydrolysis of the MWCNT-PLLA composites and following heat treatment at 550 oC under N2 atmosphere, and D) the MWCNTs obtained by alkaline hydrolysis of the MWCNT-PLLA composites. 2 Solid-phase photocatalytic degradation of polystyrene with modified nano-TiO2 catalyst Ling Zan, Songlin Wang, Wenjun Fa, Yanhe Hu, Lihong Tian and Kejian Deng, Polymer 47 (2006) 8155-8162 Fig. 1. The photographs amplified 100 times. (a) PS-untreated TiO2 film, (b) PS-g-TiO2 film (TiO2: 1%). Fig. 2. (a) The UV-vis spectra of PS-g-TiO2 (2%) films under UV-irradiation for 0 h, 15 h, 30 h, and 45 h. (b) The UV-vis spectra of pure PS films under UV-irradiation for 0 h, 15 h, 30 h, and 45 h. Fig. 3. FT-IR spectra of (a) original PS-g-TiO2 (1%), (b) pure PS irradiated for 45 h, (c) PS-g-TiO2 (1%) irradiated for 45 h. Fig. 4. XPS spectra of C1s. (a) Pure PS film (0 h), (b) pure PS film (50 h), (c) PS-g-TiO2 (TiO2: 1%) film 50 h. Fig. 4. XPS spectra of C1s. (a) Pure PS film (0 h), (b) pure PS film (50 h), (c) PS-g-TiO2 (TiO2: 1%) film 50 h. Fig. 4. XPS spectra of C1s. (a) Pure PS film (0 h), (b) pure PS film (50 h