材料导论46_塑料（Plastics）2.pptVIP

* * Advantages of BPAPC Excellent damage resistance Excellent resistance to common automobile solvents, i.e.: gasoline brake fluids刹车油 Environment-friendly (no by-products) Recyclable (thermoplastic) TP vs TS: favor recycling 再利用 Q12 * IPN plastics Cross-linked (TS) polyimide (聚酰亚胺) easy to process; brittle Linear (TP) polyimide difficult to process; tough Cross-linked (TS)＋Linear (TP) polyimide easy to process; tough ＋ Semi-IPN Interpenetrating polymer network 互穿聚合物网络 ? ? ? * Dendrimers 树枝状聚合物 A new class of spherical (particle) or rod-shaped nanostructures with hollow interiors (rod vs flexible forms; nano-纳米级) Superior coatings, adhesives, lubricants, reinforcers for composites * Block polymers Identical units clustered in blocks along the backbone chain polymer Combining the stiffness of a plastic with the toughness of an elastomer (synergy协同作用) PS PS PB thermoplastic rubber SBS, SIS 嵌段共聚物 M.7 AAAABBBBAAAA * Copolymers 共聚物 Copolymers: block copolymers嵌段 graft copolymers接枝 alternating copolymers交替 random copolymers无规 Copolymers * homopolymer; block copolymer; graft copolymer alternating copolymer; random copolymer Q13. Matching * 5.2.4 Plastic-container coding system塑料容器编号系统 Symbols on packaging container aid in sorting plastics Found on the bottom of packages other products SPI Plastic Material Code System (SPI: the Society of Plastic Industry) sorting, recycling Summary Additives Properties of plastices Processing techniques Advanced polymers Plastic-container coding system * * * * * Review * M5 Polymeric materials 5.1 Nature of polymers 5.2 Plastics 5.3 Elastomers: Natural synthetic rubbers 5.4 Adhesives other polymerics ? ? Review Preview * Semicrystalline polymers exhibit both elastic and plastic deformation. In elastic deformation - bending and stretching of covalent bonds In plastic deformation - several stages Elastic behavior deformation is recovered when a s