1基于AspenPlus粗甘油混合物的分离工艺模拟.pdfVIP

基于AspenPlus粗甘油混合物的分离工艺模拟 * 王红，傅忠君 ，孙瑞 (山东理工大学 化工学院，山东 淄博 255049) [摘 要]采用化工流程模拟软件Aspen Plus，以NRTL 热力学模型对粗甘油混合物的分离过程进行了模拟。流程采用闪蒸分子蒸馏相结合的 技术，考察了压强和温度对分离效果的影响。模拟优化的结果为：闪蒸的真空度为6.7 kPa，除去10 %的水，其中携带甘油的含量为0.5 %；分 子蒸馏的真空度为420Pa，温度为160 ℃，蒸出的甘油蒸汽的量为717.44kg/h，其中甘油的质量分数为95 %(W)，一级产品总量为626.22kg/h， 甘油纯度为99.8%(W)，二级产品总量为57.96kg/h，甘油纯度为95.8%(W)。甘油总收率达到94.6%(W)。 [关键词]粗甘油；闪蒸；分子蒸馏；流程模拟；Aspen Plus [中图分类号]TQ [文献标识码]A [文章编号]1007-1865(2014)03-0020-02 AspenSimulationandOptimizationtheSeparationofGlycerinMixture * WangHong,Fu Zhongjun ,SunRui (CollegeofChemicalEngineering,ShandongUniversity ofTechnology,Zibo255049,China) Abstract:In thepaper,the chemicalprocessuse simulation softwareAspen Pluswith NRTLthermodynamicmodel to simulatethe separationprocessof crude glycerin mixture. The process not only use flash combine with molecular distillation technology, but also investigate the effect of pressure and temperature on separation efficiency. Theresults of simulation optimization are as follows:the pressure of flash is 6.7 kPawhich carry the content of glycerolwas 0.5 % andremove 10 % of the water; molecular distillation steamed out of glycerol steam quantity is 717.44 kg/h, of which the mass fraction of glycerol was 95 %(W) under the condition ofvacuum 420Paandtemperature160 ℃;primaryproductstotalis 626.22kg/h anditsglycerin content is 99.8%(W), secondarytotalis 57.96kg/hwhich themassfraction ofglycerolis 95.8%(W).Totalyieldofglycerolreached94.6%. Keywords:crudeglycerin；flash；moleculardistillation；processsimulation；Aspen Plus 甘油主要用于医药、化妆品、醇酸树脂、烟草、食品、聚氨 的分离工艺流程模型，模型大致分为两部分，采用FL