有机半导体和研讨会.pptxVIP

有机半导体和研讨会第1页/共54页 Molecular Conducting Crystals NMP-TCNQ 　CT Mott insulator 1d AF(TCNQ) TTF-TCNQ CT 1d semimetal 　p-dep. n Peierls transition, CDW,gigantic conductivity peak, sliding conduction (CH)x Peierls insulator (Dimer)doping , carriers as ingap states (solitons) TMTCF2X CT metal ?SDW, SC, AF, Spin-Peierls, CO, ferroelectricity DCNQI2X CT metal CO(Ag), CO-Mott with Peierls (Cu) BEDTTTF2X(ET2X) CT metal Mott Insulator, Charge Ordering, SC BETS2X CT metal SC (GaCl4), Mott insulator Field-Induced SC(FeCl4) (DT-TTF)2[Au(mnt)]1/4 -filled Spin LadderCharge Ordering ?(TTM-TTP)I31 : 1 Half-filledCT metalMott TransitionI3 -- FeBr1.8Cl2.2 : Fe +3 S= 5 / 2Ni(tmdt)2 Au(tmdt)2Single Component Metal HOMO-LUMO overlap-semimetal, magnetic phase transition第2页/共54页 Peierls Transition TTF-TCNQsuperconducting fluctuationsCDW:Combined degrees of freedom of electrons and lattice distortionsCollective mode: Phason Lee-Rice -Anderson(1974) 第3页/共54页 Impurity PinningPhase Hamiltonian : HF(1976) 　= In 3d : Lee-Rice2)weak pinning : ε 1 fluctuations of potential = collective effectsCf. Larkin-Ovchinikov: vortices Parameter : ε=V0/nivF HF-Lee (1978) １）strong pinning : ε 1 第4页/共54页 “ Fukuyama - Lee - Rice ” (1987.9.4)第5页/共54页 Theory of FrictionTheoretical Studies of Friction: One-dimensional Clean Surface　　　　　 Matsukawa-HF, PRB (1994) Frenkel-Kontrova model“ Current driven magnetic domain wall motion” Gen Tatara et al., J. Phys. Soc. Jpn (2006)“Friction processes of magnetic domain with internal degree of freedom”Velocity-dependent frictional constant第6页/共54页 Molecular Conducting Crystals NMP-TCNQ 　CT Mott insulator 1d AF(TCNQ) TTF-TCNQ CT 1d semimetal 　p-dep. n Peierls transition, CDW,gigantic conductivity peak, sliding conduction (CH)x Peierls