电化学阻抗谱研究染料%2fAl2O3交替组装结构的光伏特性及作用机理.docxVIP

物理化学学报(Wuli Huaxue Xuebao) February Acta Phys.-Chim. Sin.2011,27(2),413-418 413 [Article] 电化学阻抗谱研究染料/Al?O? 交替组装结构的光伏特性及作用机理 高 瑞 马 蓓 蓓 王 立 铎 * 史 彦 涛 董 豪 鹏 邱 勇 (清华大学化学系，有机光电子及分子工程教育部重点实验室，北京100084) 摘要： 使 用Al?O? 和N3 染料制备了一种交替组装的结构，该结构能够提高染料敏化太阳能电池(DSCs) 的开路 电 压(Vo),短路电流(Jw)和转换效率(η).为了研究(染料/Al?O?)交替组装结构的作用机理，使用电化学阻抗谱技 术分析了电池的界面电阻.分析结果表明，随着交替组装结构中(染料/Al?O?)单元的增加，光阳极/染料/电解质 界面的电阻降低，电池性能随之提高.基于电化学阻抗谱分析结果，建立了一系列的等效电路模型，从理论上解 释了(染料/Al?O?)交替组装结构的作用机理. 关键词： 染料敏化太阳能电池； 交替组装结构；等效电路模型 中图分类号： 0649 Photovoltaic Properties and Mechanism Analysis of a Dye/Al?O? Alternating Assembly Structure by Electrochemical Impedance Spectroscopy GAO Rui MA Bei-Bei WANG Li-Duo SHI Yan-Tao DONG Hao-Peng QIU Yong (Key Laboratory of Organic Optoelectronics Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R.China) Abstract: N3 dye and Al2O3 were used to form an alternating assembly structure. The current density-voltage (J-V) characterization showed that this structure improved the performance of dye- sensitized solar cells (DSCs). Electrochemical impedance spectroscopy (EIS) was used to study the internal resistance of this alternating assembly structured DSCs. The results showed that the resistance at the sensitized TiO2/electrolyte interface decreased as the number of (dye/Al?O?) units increased, and the devices conversion efficiency improved significantly. Based on the EIS results, a series of equivalent circuit models were well established to investigate the dye/Al?O, alternating ass