(8296)--碱含量对新拌水泥浆体流变性能的影响.pdfVIP

碱含量对新拌水泥浆体流变性能的影响 摘 要：通过外掺硫酸钾的方式来调整不同矿物组成水泥中的碱含量，研究了碱含量对水泥/聚羧酸减水剂体系的流动度及流 变性能的影响，分析了水化初期水化产物的物相、形貌及化学组成，测定了不同碱含量条件下水泥对聚羧酸减水剂的吸附量。 结果表明：碱含量增加，新拌水泥浆体的流动度减小，屈服应力与塑性黏度增大。低铝酸三钙(C3A)含量水泥的流变性能对 碱含量的变化更为敏感，外掺硫酸碱对浆体流变性能的影响程度大于熟料中固溶的碱。水泥中高的碱含量抑制了水化初期钙 矾石的生成，过渡性水化产物钾石膏生成量增加，尤其是低 C3A 含量的水泥浆体中迅速出现大量板状钾石膏晶体，导致其流 变性能急剧下降。碱含量增加，水泥对聚羧酸减水剂的饱和吸附量增加，低 C3A 含量的水泥对聚羧酸减水剂的饱和吸附量增 加尤为明显。 Effect of Alkali Content on Rheological Properties of Fresh Cement Pastes HUANG Lei , YAN Peiyu (Department of Civil Engineering, Tsinghua University, Beijing 100084, China) Abstract: The alkali content in different cements was adjusted via adding K SO . The effect of alkali content in cement on the fluidity, 2 4 plastic viscosity, yield stress of cement/PCE system was investigated. The morphology and the chemical composition of hydration products at early age were characterized by X-ray diffraction and scanning electron microsopy-energy dispersive spectrometry. The adsorption capacity of polycarboxylate superplasticizer in cement was tested. The results show that the fluidity of the fresh cement pastes decreases and the yield stress and viscosity of the pastes increase with the increase of alkali content. The rheological properties of cement with a low tricalcium aluminate (C A)content is more sensitive to the alkali content. The effect of additive sulfate alkalis is 3 greater than that of alkalis as a solid solution of clinkers. A higher alkali content tends to facilitate the formation of syngenite and suppress the formation of ettringite (AFt), and massive tabular syngenite crystals are formed in cement pastes with a low C A content, 3 thus result