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- 2023-09-28 发布于上海
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超临界水氧化水膜反应器的热负荷特性研究的中期报告
摘要:
超临界水氧化反应器是一种高温高压的氧化反应器,广泛应用于废水处理、有机废弃物加工等领域。本研究通过实验和数值模拟研究了超临界水氧化反应器的热负荷特性,重点研究了反应器内部温度、压力、流量等参数对反应器热负荷的影响,为反应器的设计和运行提供了参考。
实验结果表明,在超临界水氧化反应器中,水的相对介电常数与压力成反比关系,随着压力升高,水的相对介电常数逐渐降低。温度对超临界水氧化反应器的热负荷影响较大,当温度达到一定值时,反应器内的反应速率和产物生成速率显著增加。流量对反应器热负荷的影响较小。
数值模拟结果表明,在超临界水氧化反应器中,内部壁面和反应物的温度分布不均匀,存在较大的温差,可以通过调整反应器的结构和流量分布来改善这种情况。另外,反应器内部沉积物的产生和积累也会对热传递和反应速率产生影响,需要注意清洗和维护。
关键词:超临界水氧化反应器;热负荷;数值模拟;实验研究
Abstract:
Supercritical water oxidation reactor is a high temperature and high pressure oxidation reactor, which is widely used in wastewater treatment, organic waste processing and other fields. In this study, the thermal load characteristics of the supercritical water oxidation reactor were studied through experiments and numerical simulations, focusing on the effects of internal temperature, pressure, flow rate and other parameters on the thermal load of the reactor, providing reference for the design and operation of the reactor.
The experimental results show that in the supercritical water oxidation reactor, the relative permittivity of water decreases with increasing pressure, and the relative permittivity of water decreases gradually with increasing pressure. Temperature has a greater effect on the thermal load of the supercritical water oxidation reactor. When the temperature reaches a certain value, the reaction rate and product generation rate in the reactor increase significantly. The flow rate has a small effect on the thermal load of the reactor.
The numerical simulation results show that the temperature distribution of the internal wall and reactants in the supercritical water oxidation reactor is uneven, and there are large temperature differences, which can be improved by adjusting the structure and flow distribution of the reactor. In addition, the generation and accumulation of deposits inside the reactor also affect heat transfer and reaction rate, which need to be cleaned and maintained.
Keywords: supercritical water oxidation reactor
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