染料敏化太阳能电池光阳极的低温制备及改性的中期报告.docxVIP

染料敏化太阳能电池光阳极的低温制备及改性的中期报告 摘要： 本文介绍了染料敏化太阳能电池（DSSC）中光阳极的低温制备及改性的中期研究进展。在低温条件下，采用溶剂热法制备了一种纳米级TiO2/n-Fe2O3复合结构光阳极，并通过表面改性提高了其光电转换性能。在改性过程中，采用了不同的改性剂，包括PEG，CTAB，以及二氧化硅等，研究了它们对光阳极表面性质和光电性能的影响。结果显示，适量的PEG改性可以显著提高光阳极的光电性能，达到最佳效果的PEG加入量为1wt%。通过比较不同改性剂的影响，可以得出，PEG改性是最优的改性方法，其原因可能是PEG可以形成有利于光电转换的介电层。此外，还研究了不同温度下制备TiO2/n-Fe2O3复合结构光阳极的性能变化，结果表明，在低温条件下制备的光阳极具有较好的光电性能。 关键词：染料敏化太阳能电池；光阳极；低温制备；表面改性；光电性能 Abstract: This paper presents the progress of mid-term research on the low-temperature preparation and modification of the photoanode in dye-sensitized solar cells (DSSCs). A nano-sized TiO2/n-Fe2O3 composite structure photoanode was prepared by solvent-thermal method under low-temperature conditions, and its photoelectric conversion performance was improved by surface modification. During the modification process, different modifiers including PEG, CTAB, and SiO2 were used to study their effects on the surface properties and photoelectric performance of the photoanode. The results showed that moderate PEG modification can significantly improve the photoelectric performance of the photoanode, and the optimal PEG addition amount was 1wt%. By comparing the effects of different modifiers, it can be concluded that PEG modification is the optimal modification method, which may be attributed to the formation of a dielectric layer favorable for photoelectric conversion. Furthermore, the performance changes of the TiO2/n-Fe2O3 composite structure photoanode prepared at different temperatures were also studied. The results showed that the photoanode prepared under low-temperature conditions had good photoelectric performance. Keywords: dye-sensitized solar cells; photoanode; low-temperature preparation; surface modification; photoelectric performance.