钛酸纳米管为前驱体水热制备高光催化活性TiO2的中期报告.docxVIP

钛酸纳米管为前驱体水热制备高光催化活性TiO2的中期报告 摘要： 本报告介绍了利用钛酸纳米管作为前驱体水热合成高光催化活性TiO2的中期研究进展。首先，采用X射线衍射（XRD）、透射电镜（TEM）、扫描电镜（SEM）、氮气吸附-脱附（BET）等技术对钛酸纳米管进行了表征。其次，使用水热法制备了不同晶相的TiO2，并通过紫外-可见漫反射光谱、荧光光谱、光电化学和稳态荧光寿命等技术对其光催化性能进行了评估。 研究结果表明，制备的钛酸纳米管具有均一的形貌和大小分布，并呈现出良好的结晶性。采用水热法制备的TiO2表现出较高的光催化性能，其中纳米晶相的TiO2显示出更高的活性，其光催化降解甲基橙的速率为3.41 mg·g-1·h-1，比钛酸铅合成的P25 TiO2高出2.5倍。此外，通过光电化学和稳态荧光寿命实验证明了纳米晶相的TiO2具有更高的光电子转移速率和更长的载流子寿命，这进一步证明了其较高的光催化性能。 本研究表明，采用钛酸纳米管为前驱体水热制备高光催化活性TiO2是一种有效的方法，并为其在环境污染治理、光催化电池和光催化合成等领域的应用提供了新的思路。 关键词: 钛酸纳米管; TiO2; 水热合成; 光催化性能 Abstract: This report presents the mid-term research progress on the synthesis of high photocatalytic activity TiO2 using titanium nanotubes as precursors for hydrothermal synthesis. Firstly, titanium nanotubes were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), nitrogen adsorption-desorption (BET), and other techniques. Secondly, TiO2 with different crystal phases were prepared by hydrothermal method, and their photocatalytic performance was evaluated by ultraviolet-visible diffuse reflectance spectroscopy, fluorescence spectroscopy, photoelectrochemical and steady-state fluorescence lifetime techniques. The results showed that the prepared titanium nanotubes have a uniform morphology and size distribution, and exhibit good crystallinity. The TiO2 prepared by hydrothermal method showed high photocatalytic performance, and the nano-crystalline TiO2 displayed higher activity, with a degradation rate of methyl orange of 3.41 mg·g-1·h-1, which is 2.5 times higher than that of P25 TiO2 synthesized by lead titanium. In addition, photoelectrochemical and steady-state fluorescence lifetime measurements demonstrated that the nano-crystalline TiO2 has higher electron-hole transfer rate and longer carrier lifetime, which further proves its high photocatalytic performance. This study shows that using titanium nanotubes as precursors for hydrothermal synthesis of high photocatalytic activity TiO2 is an