蒽的亚甲基二硫醚的合成.docVIP

蒽的亚甲基二硫醚的合成 ---------------------------------------------------------------范文最新推荐------------------------------------------------------ 蒽的亚甲基二硫醚的合成 摘要:近年来对二硫醚的研究逐渐加大，其结构通式为RSSR#39;，化学性质稳定。二硫醚类化合物是食品香料的重要成分，同时也是有机化学反应中的重要中间体。在有机合成、高分子、医药行业等领域应用非常广泛。本论文主要介绍一种全新的二硫醚即蒽亚甲基二硫醚的合成。合成方法是9-蒽醛在一氧化碳、水和碱的条件下先还原生成硫醇，然后硫醇经氧化再生成二硫醚。该方法的反应条件温和，溶解于有机溶剂DMF中，在常压、95?左右即可反应，该操作简便，选择性强且产率高。得到产物后，再进行定性和定量分析，通过氢谱和碳谱对产物进行表征，确定其结构,通过特征峰可预测产物的光学性质,通过测定含量求得产率。10877 关键词:二硫醚,一氧化碳;产率 The Synthesis of Anthracene Methylene Disulfide Ether 1 / 5 Abstract: In recent years the study of disulfide ether has gradually increased,the structural general ormula of it is RSSR #39; and it has stable chemical properties, Dsulfide ether compounds are important components of food flavors and they are important intermediates in organic chemistry reaction and they have very extensive application in organic synthesis, polymer, pharmaceutical industry,This article mainiy introduces a new disulfide ether named anthracene methylene disulfide ether,Synthesis method is that9 - anthracene aldehyde in the condition ofcarbon monoxide，water and alkali can get mercaptan reduction then Mercaptan was oxidized to disulfide ether,The method of this reaction has mild reaction conditions,Dissolved in organic solvent DMF and around 95 ? can react and this method has many advantages such as Easy to operate,Strong selectivity and highproduction rate.After getting the product，then we nend to do some qualitative and quantitative analysis,The product was characterized by 1H NMR and 13C NMR,The characteristic peaks can predict the optical properties of the product,Through the determination of ---------------------------------------------------------------范文最新推荐------------------------------------------------------ yield we can get production rate, 1 二硫醚的合成方法简介 1.1硫醇氧化法 Shaabanig[9]等人研究了在无溶剂的条件下，可以用高锰酸盐将硫醇氧化为相应的二硫醚。以高锰酸钾为氧化剂，在室温下反应10-20分钟可以将环己硫醇氧化为二环己基二硫醚，产率为95,。 硫醇已在其它常用氧化剂条件下如二氧化锰[10]，过氧化氢[11]，二甲基亚砜[12]，水合肼[13]，碘[14