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JournalofHazardousMaterials283(2015)574–581
ContentslistsavailableatScienceDirect
JournalofHazardousMaterials
journalhomepage:www.elsev/locate/jhazmat
Identificationofchlorinatedoligomersformedduringanodic
oxidationofphenolinthepresenceofchloride
LinxiChen,PabloCampo,MargaretJ.Kupferle∗
DepartmentofBiomedical,ChemicalandEnvironmentalEngineering,UniversityofCincinnati,701BERCbuilding,2901WoodsideDr.,Cincinnati,
OH45221,UnitedStates
highlightsgraphicalabstract
•By-productsfromanodicoxidationof
phenolinthepresenceofchlorideare
investigated.
•Chlorinatedoligomerformationis
demonstratedbyLC-QTOF-MS.
•Theyhavestructuressimilartotri-
closanandpolychlorinateddibenzo-
p-dioxins.
articleinfoabstract
Articlehistory:Chlorinatedoligomerintermediatesformedduringtheanodicelectrochemicaloxidationofphenolwith
Received10July2014aboron-dopeddiamondelectrodewerestudiedattwodifferentconcentrationsofchloride(5mMand
Receivedinrevisedform50mM).Underthesameionicstrength,withsodiumsulfatebeingthemake-upion,a10-foldincreasein
16September2014Cl−ledtoremovalrates10.8,1.5,and1.4timeshigherforphenol,TOC,andCOD,respectively.Mono-,di-
Accepted1October2014
Availableonline13October2014andtrichlorophenolsresultingfromelectrophilicsubstitutionweretheiden
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