物理研究中核仪器方法介绍.pdfVIP

NuclearInstrumentsandMethodsinPhysicsResearchA470(2001)336–340

Stabilizationofheavymetalcationsintheframeworkof

zirconiumphosphates

V.V.Kriventsov*,D.I.Kochubey,V.A.Sadykov,S.N.Pavlova,

G.V.Zabolotnaya

BoreskovInstituteofCatalysis,SBRAS,Pr.Lavrentieva,5,630090Novosibirsk,Russia

Coordinationformsofheavymetalcations(suchasPt,MoandW)intheframeworkofzirconiumphosphatesand

theirinfluenceonthematrixstructurewerestudiedbytheEXAFSmethod.Additionalstabilizingcations(LaandSiin

ourcase)areusuallylocatedinthestructureofzirconiumphosphates.Itisshownthatthebasicsitesofcation

stabilizationintheframeworkofzirconiumphosphatesarethepositionsofthesecondcations.OxideparticlesMeOx

cangrowatsuchsitesifthesorptioncapacityofzirconiumphosphatesisnotenoughforstabilizationoftheentire

amountofheavymetalcations.r2001ElsevierScienceB.V.s.

PACS:61.10Ht;82.65Jv;82.65My;82.70Gg

:EXAFS;Nanoparticles;Nanocomposites;Frameworkzirconiumphosphates

1.IntroductionInourearlierworks[2–4],theprocedureswere

developedforthesynthesisofhighlydispersed

Recentlygreatattentionhasbeengiventosuchmesoporousframeworkzirconiumphosphatesvia

catalyticsystemsforacidcatalysisashydrothermaltreatmentinthepresenceofpoly-

frameworkzirconiumphosphateswiththeNZP-ethyleneoxideofamorphoussolsortheproductsof

typestructure.Accordingtothework[1],theH-