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•PolyamideMacromolecule
•AmorphousInfraredspectroscopy
•X-rayDiffractiondisentanglement
•MeltstrengthReciprocatingscrew
•PolyurethaneViscoelasticbehavior
•AmorphousX-rayDiffraction
•DifferentialScanningCalorimetry
•Coefficientofthermalexpansion
•Vicatsofteningtemperature
•Molecularweightdistribution
•Compressionmolding
•Liquidcrystal
•Yieldstrength
•Ejectionsystem
•1.Insomecases,thepolymermoleculescanpack
togetherintoregular,repeatingstructuralpatterns.These
regularlypackedregionsarecalledcrystalsorcrystalline
regions.Althoughnopolymeriscompleycrystalline,
thosewithlargepartofcrystallineareasaresaidtobe
crystallineorsemicrystalline.
•2.Polymerchainsaregenerallysolongthatsignificant
intermolecularentanglementexistsevenintheliquid
state.Thisentanglementintheliquidstateihibitedin
thehighviscosityofthepolymermeltsandsolutionsand
inapropertycalledmeltstrength.
•3.Animportantthermaltransitioninthecrystalline
polymersisatthemetingpoint,wherethepolymer
moleculescanmovely.Beyondthemeltingpoint,
furtherheatingwilleventuallycausethemoleculeto
degradebecausethethermalenergyissufficientto
breaktheprimarybondsofthemolecules.
•4.Mostviscoelasticmaterialswillalsoshowsignificant
deformationswithstaticloadsbutoverlongperiodof
time.Thispropertyiscalledcreep,definedasthe
gradualdeformationofamaterialunderastaticload.
•5.Animportantparamessociatedwiththescrewis
theratioofthelengthoftheflightedportionofthescrew
totheinsidediameterofthebarre
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