分子轨道理论杂化.pdfVIP

戆冺皟沓5.12,鋯嗧被3,2003肀?沓?0砭

Chemistry5.12,Lecture#3,2/10/03

砘汇拞

Outline

III.ReviewofMolecularOrbitalTheory(ReadChapter2)

砜氻搐鋽间槯猝氫啂砘⌒此勪瘷鋰忋剙褷銈此

A.AtomicOrbitals(2-1)

淼稠搐鋽间槯(2-1)

B.Sigma-Bonding(2-2A)

鲁洮?2-2A)

C.Pi-Bonding(2-2B)

卤洮?2-2B)

D.VSEPRTheory(2-4)

計砀栤瑝泶ろ穽薛斫光鋯?VSEPR)(2-4)

IV.Hybridization/LCAO

泶栱唱/淼稠搐鋽间槯銙擁坊銙橅窚锛圠CAO锛

A.spHybridization(2-4A)

泶栱唱(2-4A)

B.sp2Hybridization(2-4B)

泶栱唱(2-4B)

C.sp3Hybridization(2-4C)

泶栱唱(2-4C)

1.RotationofEthaneversusEthylene(2-3,7,8)

协鉀嬳範协鉀冺緹鋾€袩矸嶁啫(2-3,7,8)

ProblemSet#1DueTodayby4pm

覟砘较燀礈4鈿嵪炑感翠宫洳氻皢1

ProblemSet#2Posted:DueTuesday(2/18/03)

砜椼晜写涔?2锛毾燀讣褷蠟迅(2003骞?鏈?8鏃?

淼笺い涔硞藮

SuggestedProblems:2-28,29,31,33

浏欎噺沓濏磶砜氻搐銙夈緶

*Read2-12,13:SurveyofOrganicMolecules

III.MolecularOrbitalTheory

砜氻搐鋽间槯猝氫啂

猬夗搐戆兿斺尽鈯妒

ElectronsAreWaves!

淼椨€夜蠞銚堝亸鈯垛睒泶俄常泶臣戆嬩敿錁ы皩

TheyExistas3-DStandingWaves(Orbitals).

淼稠搐鋽间槯锛氬師瀛愪腑鏈潅鍖栫殑杞ㄩ亾(s,p,d)spd

atomicorbitals:unhybridizedorbitalsonanatom(,,)

淼稠搐鋽间槯銙擁坊銙橅窚藮猓€銈熲睒鋽间槯鈯俄繎斫勴皨鋽间槯戆屸硨薛銙橅窚泶俄郡褮淼稠搐獗橅礀沓敿錁

LinearCombinationofAtomicOrbitals(LCAO):Individualwave

23

(sp,sp,sp)夜矶烅繗泶や敿錁?蟽,蟽鈭?蟺,蟺鈭?23

spspsp

functions(orbitals)combinetoformhybridatomicorbitals(,,)

andmolecularorbi