5第五章 非金属原子簇.pptVIP

三.硼烷的骨架电子对规则(Wade规则)硼烷结构和骨架电子对数的关系四.碳硼烷及金属碳硼烷衍生物五.富勒烯(Fullerenes)（碳原子簇）化学六.碳纳米管(carbonnanotube)InorganicChemistry2001,coverSalutetoFredHawthorneIcosahedralB12H122–40yearsC6032面体IhC70D5d热力学稳定性比石墨差可被还原和自由基、亲核试剂加成和化学修饰13CNMRspectrumofthepurifiedC60,reportedbyKrotoetal.(Taylor,1990).TheNMRspectrumcontainedasinglepeakat142.7,asexpectedforthehighlysymmetricaltruncatedicosahedronstructureinwhichallcarbonsareidenticalDefinitiveproofforthestructureofC60camein1991whenJoelHawkins(Univ