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《新能源技术与材料》第22章Perovskite-Based Solar Cell.pptx

《新能源技术与材料》第22章Perovskite-Based Solar Cell.pptx

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Perovskite-BasedSolarCell

CONTENTSBackgroundofPerovskitePerovskiteinsolarcellMechanismResearchprogressOpenquestions

1.BackgroundofPerovskite?Perovskite-CaTiO3isometricsystem(ABO3)organometaltrihalideperovskite:(RNH3)BX3(RisCnH2n+1,XisthehalogenI,BrorCl,andBisPborSn)Aismethylammonium,BisPbandXisIorCl.MingzhenLiuet.al.nature.2013//GaryHodes.science.2013?CH3NH3PbI31.highercharge-carriermobilitiesHighchargecarrierlifetime(TRTAPL)//longereffectivediffusionlengths(~1um)2.LowtemperaturesolutionmethodsCo-deposition,Spin-coating,vacuumvapordeposition,two-stepdeposition3.HigherVocpervoskite,lossesamountonlyabout0.4ev

2.Perovskiteinsolarcell?DSSCs→Solid-StateDSSCsHybridperovskiteABX3(Lightharvester)Liquid—ABX3(CH3NH3PbI3/Br3assensitizers)dissolveintheelectrolytesGaryHodes.science.2013//DongqinBiet.al.J.Phys.Chem.Lett.2013//MingzhenLiuet.al.nature.2013//RobertF.science.2013MolecularstructuresofdifferentHTMs(holetransportmaterialsp-typeholetransporter)

3.MechanismTheprototypesolidstateDSSCSolidstateDSSCwithap-typesemiconductortoreplacetheelectrolytecontainingtheredoxcouple.DiWei.Int.J.Mol.Sci.2010

n-typecompact:electroncollectorhole-blockingDongqinBiet.al.RSCAdv.2013//LiozEtgaret.al.J.Am.Chem.Soc.2012//J.H.Heoet.al.Nat.Photonics.2013.?ElectronsexcitedintheperovskiteinjectedintotheTiO2?CH3NH3PbI3exhibitsanambipolarcharacter(predominantlyp-type)0.1ev100compactfilm/500nmnanosheets

4.Researchprogress?QD-SensitiedSolarcell?Perovskite-BasedSolid-StateDSSCsMethodsHTMsN-typecompactlayerCounterElectrode

?QD-SensitizedSolarcellQD-arrayedp-i-njunctionsolarcell?QD-SensitizedsolarcellQD-embeddedpolymersolarcellJeong-HyeokImet.al.Nanoscale.2011η%JSC(mA·cm-2)Voc(V)FFArea(cm2)S16.2015.990.6290.6170.309S26.5415.820.70

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