哈粘土扩大纳米管腔通过选择性蚀刻氧化铝科技英语交流qinlijuan.pptx

EnlargementofHalloysiteClay

NanotubeLumenbySelectiveEtching

ofAluminumOxide

Reporter：LijuanQin

Data：2015.11.04

Abdullayevet.al.ACSNANO.2012,6,7216–7226

Contents

Background

Experimental

Resultsanddiscussion

Conclusion

2

Background

1.AchemicalformulaofAl2Si2O5(OH)4·2H2O.

2.Externaldiameterofhalloysitenanotube(HNT)isca.50nm,theinnerdiameteris10-15nm,and500-1000nminlength.

3.Anabundantlyavailablenaturalnanomaterialatlowprice.

YuriLvovet.alAdv.Mater.DOI:10.1002/adma.201502341

3

1.CellSurfaceDepositionviaLbLPolymerAssembly.

2.HalloysiteasanAdsorbent.

3.HalloysiteMesoporousTemplatesforCatalytic.Nanoparticles.

4.FunctionalComposites:Phase-ChangeMaterials(PCMs)

forThermal-EnergyStorage.

4

Experimental

HalloysiteEtchingbySulfuricAcid.Onegramofhalloysitewasdispersedin100mLofsulfuricacidof0.5,1.0or2.0M.Suspensionwasmagneticallystirredonahotplateatthecontrolledtemperaturesbetween40and90℃.Onemilliliteraliquotsweretakenatcertaintimeintervalsandcentrifugedtoseparatehalloysites.Then,halloysitewaswashed5timeswithDIwater.ThepHofthesupernatantfromthefinalwashingstagewasintherangeof6-7,whichissimilartothatofpurehalloysitesuspension.Samplewasdriedintheovenat50℃.Finalsamplerepresentedawhitesolidthatwaseasilycrushedintopowderusingmortar.

5

Resultsanddiscussion

Themechanismofacidetching:

6

Resultsanddiscussion

Tubemorphologydependingonpercentageofremovedalumina:

tubularmorphology

porousnanorods

completeremovalofthealumina

7

Resultsanddiscussion

8

Resultsanddiscussion

FT-IRspectra:

Al-OH:3620and3690cm-1dissapearuponproceedingofthereaction,indicatingtheremovalofaluminalayers.

SiO-Hvibrations:abroadpeakat3200-1-3700cm-1range,indicatingtheformationofsilicananoparticles.

X-raydiffractionpatterns：

A4.5Åreflection,anothercharacteristicof