电活化过硫酸氢钾耦合超滤体系去除小分子溶解性有机污染物及缓解膜污染研究.pdfVIP

重庆大学硕士学位论文摘要

列表征分析，上述强氧化性活性物种可降低出水溶液中疏水组分所占比例，减小

污染物粒径尺寸，提高受污染膜亲水性。总的来说，E-PMS-UF体系的强膜污染缓

解能力主要归因于电斥力以及活化PMS产生的活性物种。

综上所述，本研究提出了一种新型的E-PMS-UF体系，用以去除水体中小分

子有机污染物并缓解膜污染，解释了该体系的反应机理，为后续将电活化过硫酸

氢钾应用于超滤工艺中提供了一定的理论参考和借鉴意义。

关键词：高级氧化技术；过硫酸氢钾；电化学；超滤；膜污染

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重庆大学硕士学位论文Abstract

Abstract

Ultrafiltration(UF)processisaseparationperformancebetweenmicrofiltration

andnanofiltrationmembraneseparationtechnologylow-pressuremembrane,whichhas

theadvantagesofsimpleoperation,lowoperatingpressureandgoodreusability,andis

widelyusedinadvanceddrinkingwatertreatment,petroleum,anddairyproduction

industries.However,thepoorretentioneffectofsmallmoleculeorganicpollutants

(SMOP)andtheseriousproblemsofmembranefoulinghavealwaysbeenobstaclesthat

limitthedevelopmentofultrafiltrationtechnology.Inordertosolvetheabovetwo

problems,anelectroactivatedperoxymonosulfate(E-PMS)coupledultrafiltration

(E-PMS-UF)processwasbuilttoremovecarbamazepine(CBZ)inwaterandalleviate

membranefouling.Theefficacyofdifferentprocesssontheremovalofsmallmolecule

organicpollutantsinwaterandthemitigationofmembranefoulingwereanalyzed.The

effectsofperoxymonosulfate(PMS)concentration,currentdensityandinitialpHonthe

removalofCBZandthealleviationofmembranefoulinginE-PMS-UFprocessswere

investigated.TheremovalmechanismofCBZbyE-PMS-UFprocesswaspreliminarily

explored.Finally,themechanismofmembranefoulingalleviatingE-PMS-UFprocess

wasexploredthroughaseriesofcharacterizationexperiments.Themainconclusionsof

thestudyareasfollows:

(1)ThestudycomparedtheremovalefficacyofdifferentprocesssonCBZ,under

thebestworkingconditions,the