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Chapter
2
TheoriesofAdhesion
2.1Introduction
Thereisnounifyingsingletheoryofadhesiononwhichtoaccurately
modelallinteractionsthattakeceweentheadhesiveandthe
adherend.Theexistingtheoriesofadhesionpresentedinthischapter
providemethodsbywhichonecanrationalizepracticalobservations.
Theyaregenerallyusefulinunderstandingwhyadhesivesstickand
why,attimes,theyfail.Adhesiontheoriesallowustomakepredic-
tionsandevenobtainaqualitativerealizationofjointstrength.
Thereareseveraltheoriesofadhesionthathaveenduredthetestof
time.Eachisapplicableincertaincircumstances,butnoneareuni-
versallyapplicable.Bybeingfamiliarwiththesetheories,onecande-
velopaknowledgebaseandanawarenessofhowadhesivesandseal-
antsworkinpracticalsituations.
2.2ForcesInvolvedinAdhesion
Theforcesinvolvedinholdingadhesivesandsealantstotheirsub-
stratesorinholdingadhesivesandsealantstogetherasabulkma-
terialarisefromthesameorigins.Thesesameforcesareallaroundus
innature.Tounderstandwhatishappeninginanadhesiveorseal-ant
joint,wemustfirstunderstandtheforcesthatbindatomsand
molecutogether.Althoughtherearemanykindsofforces,itis
mainlythoseofaphysic
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