PE原料及PE管道发展现状及趋势.docxVIP

(formerlyATOFINA)

WHERE,WHEN,andWHICHHDPE

WHY…forPIPES

CHINANATIONALSTANDARDSSeminarBeijing,26-27June2005

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GOLDENJUBILEE

50YearsHDPE

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SOMEAPPLICATIONS

CableBlowMolding

Film,Sheet,Profile Rotomolding

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PIPEandFITTINGAPPLICATION

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MANUFACTURING

ETHYLENE POLYETHYLENE

nCH2=CH2 -[CH2–CH2]n-

CATALYSTCOMONOMER

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COMONOMERSYSTEMS

\C

/C

\C

/C

\C

/C

\C

/C

\C

/C

\

Homopolymer

\C

/C

\C

/

CC\/

C–C/

C\

C/

C\

C/

C\

ButeneCopolymer

\C

/C

\

C C//

C C-C\/

C-C/

C\

C/

C\

C/

C\

HexeneCopolymer

\C

/

CC\/

C C-C//

C C-C\/

C–C/

C\

C/

C\

C/

C\

OcteneCopolymer

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CRYSTALLINITY

Amorphousstructure,e.g.PVC,ABS,…

Semi-crystallinestructure,e.g.PE,PP,PA,PC,…

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CRYSTALLISATIONPRINCIPLE

Thecomonomerbranchesdisturbthecrystallisation.Hexenehasamuchhigherefficiencythanbutene

TotalPetroc.GustaafSUYSTotalPetro

TotalPetroc.

GustaafSUYS

TotalPetro

R hFl

DUCTILEFAILUREMECHANISM

1

Re:ArnoldLUSTIGER

1

2

Failurebybreak:tensiletestfailure

2Failurebysplitting:pressuretesting

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BRITTLEFAILUREMECHANISM

1

Re:ArnoldLUSTIGER

1IntercrystallinefailurebySCG

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MWD:MONOMODAL

Comonomer

Thehighestcontentofcomonomerisinthelowestmolecularweightportion,whichisnottheoptimalconditionforhighstrengthmaterial

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MWD:BIMODAL

MWDAB

MWDA MWDB

ComonomerinB

ComonomerinAB

AsonlyportionBiscopolymer,itwillleadtohighcomonomerbranchinginthehi