AZ31B镁合金表面镍基复合镀层的制备及耐蚀性能研究.docxVIP

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2024年第53卷第10期

Vol.53No.102024

热加工工艺

HotWorkingTechnology

ISSN1001-3814CN61-1133/TG

DOI:10.14158/j.cnki.1001-3814. rjggy@

AZ31B镁合金表面镍基复合镀层的制备

及耐蚀性能研究

李昆达1,张建强2,赵慧敏1,范爱兰1,班美丽1

(1.太原理工大学材料科学与工程学院,山西太原030024;2.山西能源学院,山西晋中030604)

摘要院为了提高镁合金的耐腐蚀性袁以AZ31B镁合金为基体袁采用化学镀与脉冲电镀技术在其表面制备了Ni-P/Ni复合镀层遥采用扫描电镜渊SEM冤尧X射线衍射渊XRD冤分析了镀层表面的形貌和成分遥通过电化学极化尧阻抗测试和接触角研究了该复合镀层的耐腐蚀性和疏水性遥结果表明院峰值电流密度为30mA/cm2时袁镀层的晶粒最细致袁接触

角最高为117.3毅袁自腐蚀电位最高渊-0.4510V冤袁腐蚀电流密度最低渊1.94伊10-7A/cm2冤袁阻抗值最大袁明显优于镁合金基

体袁这说明该复合镀层可提高镁合金疏水性和耐腐蚀性遥

关键词院镁合金曰化学镀曰脉冲电镀曰耐腐蚀性曰疏水性

中图分类号院TG178 文献标识码院A 文章编号院1001-3814(2024)10-0022-06

ResearchonPreparationandCorrosionResistanceofNickel-basedCompositePlatingonAZ31BMagnesiumAlloySurface

LIKunda1,ZHANGJianqiang2,ZHAOHuimin1,FANAilan1,BANMeili1

(1.CollegeofMaterialsScienceandEngineering,TaiyuanUniversityofTechnology,Taiyuan030024,China;2.ShanxiInstituteofEnergy,Jinzhong030604,China)

Abstract院Inordertoimprovethecorrosionresistanceofmagnesiumalloy,Ni-P/Nicompositecoatingwaspreparedon

thesurfaceofAZ31Bmagnesiumalloyusingchemicalplatingandpulseplatingtechniques.Scanelectronmicroscope(SEM)andX-raydiffractometer(XRD)wereemployedtodetectthesurfacemorphologyandcompositionofthecompositecoating.Besides,thecorrosionresistanceandhydrophobicityofthecompositecoatingwereinvestigatedbyelectrochemicalpolarization,impedancetestsandcontactangletests.Theresultsshowthatwiththepeakcurrentdensityof30mA/cm2,thecoatinghasthemostdetailedgrain,thehighestcontactangleof117.3毅,thehighestself-corrosionpotential(-0.4510V),the

lowestcorrosioncurrentdensity(1.94伊10-7A/cm2),andthelargestimpedancevalue,whichisobviouslybetterthanthatofthe

magnesiumalloymatrix,indicatingthatthecompositecoatingcouldimprovethehydrophobicityandcorrosionresistanceofmagnesium