影响电池性能的因素：金属离子溶剂化结构衍生的界面行为还是固体电解质界面膜_(1).pdfVIP

电化学

J.Electrochem.2022,28(11),2219012(1of23)

[Review]DOI:10.13208/j.electrochem.2219012

WhichFactorDominatesBatteryPerformance:MetalIonSolvation

Structure鄄DerivedInterfacialBehavioror

SolidElectrolyteInterphaseLayer

1,213311,2*

Hao-RanCheng,ZhengMa,Ying-JunGuo,Chun-ShengSun,QianLi,JunMing

(1.StateKeyLaboratoryofRareEarthResourceUtilizationChangchunInstituteofAppliedChemistry,

ChineseAcademyofSciences,Changchun130022,Jilin,China;2.SchoolofAppliedChemistryand

EngineeringUniversityofScienceandTechnologyofChina,Hefei230026,Anhui,China;

3.HuzhouKunlunEnchemBatteryMaterialsCo.,Ltd.,Huzhou313103,Zhejiang,China.)

Abstract:Solid-electrolyteinterphase(SEI)layerformedontheelectrodebyelectrolytedecompositionhasbeenconsidered

tobeoneofthemostimportantfactorsaffectingthebatteryperformance.Wediscoverthatthemetalionsolvationstructurecanalso

influencetheperformance,particularly,itcanelucidatemanyphenomenathattheSEIcannot.Inthisreview,wesummarizetheim-

portanceofthemetalionsolvationstructureandthederivedmetalionde-solvationbehaviors,bywhichwecanbuildaninterfacial

modeltoshowtherelationshipbetweentheinterfacialbehaviorandelectrodeperformance,andthenapplytodifferentelectrodeand

batterysystems.Weemphasizetheinfluencesofionicandmolecularinteractionsonelectrodesurfacethatdifferfromprevious

SEI-basedinterpretations.Thisreviewprovidesanewviewangletounderstandthebatteryperformanceandguidetheelectrolyte

design.

Keywords:battery;electrolyte;solvationstructure;electrodeinterfacialmodel;solidelectrolyteinterphaselayer

1Introductionthedevelopmentoflithium-ionbatteries(LI