铝与Cu-P合金熔体互溶过程中过渡层熔体凝固组织的研究.docxVIP

《热加工工艺》2020年1月第49卷第2期

铝与Cu-P合金熔体互溶过程中过渡层熔体凝固组织的研究

任为,陈淑英,李青春,常国威(辽宁工业大学材料科学与工程学院,辽宁锦州121001)

摘要：将纯铝熔体倒入Cu-P合金熔体，保温30s后用水激冷。采用Axiovert200MAT金相显微镜和MLA250（FEIQuanta）扫描电镜（附带能谱仪）观察金相组织，并进行能谱分析。研究了铝与Cu-P合金熔体互溶过程中过渡层熔体的凝固组织，并分析了铝、铜和磷原子的扩散过程。结果表明：铝与Cu-P合金熔体接触后形成的过渡层由L(Cu-Al-P)+L(Cu-Al)+AlP组成，凝固后靠近Cu-P合金一侧的凝固组织为Cu3P初生+(αCu+Cu3P)共晶+少量的AlP；由于Cu-P合金为过共晶成分，凝固后靠近Cu-P合金一侧P/Cu比变大，使Cu-P合金的过共晶程度增大，凝固组织中初生Cu3P相数量增多。

关键词：Al-Cu-P中间合金；熔体互溶；扩散；过渡层；凝固组织DOI:10.14158/j.cnki.1001-3814.中图分类号：TG146.21 文献标识码：A 文章编号：1001-3814(2020)2-0039-04

StudyonSolidificationStructureofTransitionLayerMeltDuringMiscibilityProcessofAlandCu-PAlloyMelts

RENWei,CHENShuying,LIQingchun,CHANGGuowei

(SchoolofMaterialsScienceandEngineering,LiaoningUniversityofTechnology,Jinzhou121001,China)Abstract：ThepurealuminummeltwaspouredintoCu-Palloymelt,andthenthemixedmeltwascooledbywaterafter

30sheatpreservation.Axiovert200MATmetallographicmicroscopeandMLA250FEIQuantascanningelectronmicroscope（attachedspectrometer）wereusedforthemicrostructureobservationandenergyspectrumanalysis,andthesolidificationstructureofthetransitionlayermeltduringthemiscibilityprocessbetweenAlandCu-Pwasstudied,andthediffusionprocessofAl,CuandPatomswasanalyzed.TheresultsshowthatthetransitionlayeriscomposedofL(Cu-Al-P),L(Cu-Al)andAlPwhenAlcontactswithCu-Palloy.Afterthesolidification,thestructurenearthesideofCu-PalloyisprimaryCu3P,eutectic(αCu+Cu3P)andasmallamountofAlP.DuetothehypereutecticcompositionofCu-Palloy,theP/CurationearthesideofCu-Palloyincreasesafterthesolidification,whichcanincreasethehypereutecticdegreeofCu-PalloyandthenumbersofprimaryCu3Pphase.

Keywords：Al-Cu-Pmasteralloy;meltmiscibility;diffusion;transitionlayer;solidificationstructure

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