二氧化氯的水净化氧化工艺（特别篇）二氧化氯在油田回注水处理中的作用.pdfVIP

WHITESustainableBiocideStrategies:

PAPER:ClO₂inProducedInjection

WaterTreatment

Producedandinjectionwatersystemsareessentialtotheproductivityandlongevityofoilandgas

reservoirs.However,theyalsopresentapersistentchallenge:theproliferationofsulfate-reducing

bacteria(SRB),acid-producingbacteria(APB),andothermicrobialspeciesthatpromotesouring,

scaling,andmicrobiologicallyinfluencedcorrosion(MIC).Fordecades,theindustryhasreliedon

conventionalbiocidessuchasglutaraldehydeandtetrakis(hydroxymethyl)phosphoniumsulfate

(THPS).Whileeffective,thesechemistriesposesustainabilityandsafetyconcerns,including

residualtoxicity,poorbiodegradability,andhighchemicaloxygendemand(COD).

Chlorinedioxide(ClO2)hasemergedasahigh-performance,environmentallyresponsiblealternative

formicrobialcontrolinproducedandinjectionwatersystems.Itsselectiveoxidationmechanism

allowsittoeliminatesulfide,biofilms,andmicroorganismswithoutgeneratingchlorinated

by-products.ThiswhitepaperexploresresearchandfielddatademonstratinghowClO2provides

sustainableandeffectivetreatmentperformanceacrossoilfieldwaterapplications.

THELIMITATIONSOFCONVENTIONALBIOCIDES

Traditionalaldehyde-basedandquaternaryammoniumbiocidesactprimarilybydisruptingcell

membranesandmetabolicenzymes.However,thesecompoundsrequirehighdoses,extended

contacttimes,andrepeatedtreatmentduetomicrobialadaptationandresistantbiofilmformation.

Theycanalsopersistintheenvironment,introducingtoxicityriskstoaquaticlifeandincreasing

post-treatmentdisposalchallenges.

Incontrast,ClO2actsthroughanoxidativepathwaythatdisruptsbothplanktonicandsessile

microbialcommunitiesbyoxidizingcellwalls,sulfides,andEPSmatrices.Becauseitisgenerated

on-siteanddecompos