OLED器件结构与工作原理精要.pptxVIP

ElectrontransportlayerHoletransportlayerAnodeSubstrateEmissivelayerElectronInjectionlayerCathodeHoleInjectionlayerHOMO—EvLUMO—EcTransparentsubstrateITOHILHTLEMLETLEILCathodeh+e-h+h+e-e-LightElectronsinjectedfromcathodeHolesinjectedfromanodeTransportandradiativebinationofelectronholepairsatemissivelayer1SmallmolecularOLEDs—DeviceoperationprincipleHOMO,LUMOoftheHTLisslightlyabovethatoftheETL

n-typematerials(ElectronInjectionLayer)Alq3:tris(8-hydroxyquinoline)aluminumElectronTransportLayerPBD:2-(4-biphenyl)-5-(4-t-butylphenyl)-1,3,4-oxadiazolep-typematerialsHIL(HoleInjectionLayer):NPBHTL(HoleTransportLayer):TPDEML:(EmmisiveLayer)Fluorescentdye:DCM2PhosphorescentdyePtOEP,Ir(ppy)3

2MolecularLuminescenceFluorescence:absorptionofphoton,short-livedexcitedstate(singlet),emissionofphoton.Phosphorescence:absorptionofphoton,long-livedexcitedstate(triplet),emissionofphoton.Chemiluminescence:noexcitationsource–chemicalreactionprovidesenergytoexcitemolecule,emissionofphoton.TripletexcitedstateTheexcitedvalenceelectronmayspontaneouslyreverseitsspin(spinflip).Thisprocessiscalledintersystemcrossing.ElectronsinbothorbitalsnowhavesamespinorientationSingletexcitedstate:Electroninhigherenergyorbitalhastheoppositespinorientationrelativetoelectroninthelowerorbital

PrinciplesofFluorescenceFluorescenceprocess:Non-radiativerelaxationIntheexcitedstate,theelectronispromotedtoanantibondingorbital→atomsinthebondarelesstightlyheld.Vibrationaldeactivationtakesplacethroughintermolecularcollisionsatatimescaleof10-12s(fasterthanthatoffluorescenceprocess).SoS1SoS1Fluorescenceprocess:EmissionThemoleculerelaxesfromthelowestvibrationalenergyleveloftheexcitedstatetoavibrationalenergylevelofthegroundstate(10-9s)Relaxationtogroundstateoccursfasterthantimescale