第八章：理想二元液体混合物及其相图.pptxVIP

Chapter8Phasediagrams

8-1IdealbinaryliquidmixtureBinarymeanstwocomponents.Idealmeanstwokindsofliquidcancompletelydissolvewitheachothertoformidealsolution.Forponentsystem,F=C-p+2=2-p+2=4-pIfp=1,thebiggestdegreeoffreedomis3(T,PandX);F*=C-p+1=2-p+1=3-pIfp=1,thebiggestdegreeofconditionfreedomF*is2(T-P,T-X,P-X);

1.Vaporpositiondiagram(P-X)a.P-XAdiagramEachcomponentinidealsolutionobeysRaoult’slaw.Forthebinaryidealsystem,PA=PA°XAPB=PB°XBPtotal=PA+PB=PA°XA+PB°XB=PA°XA+PB°(1-XA)=(PA°-PB°)XA+