第四周第6章：理想气体简单状态变化及熵变计算.pptx

4-5Calculationonentropychange

1.Simplestatechange

SimplestatechangesarethechangesinstateorinP，V，Tforidealgas，notincludingphasechangesandchemicalreactions。a.Isothermalreversibleprocess

b.??Isothermalirreversibleprocess（vacuumexpansion）Qreal=0，W=0，ΔU=0Sotheexpansionofidealgastovacuumisanirreversibleprocess。

c.IsothermalexpansionatconstantexternalpressureΔU=0Qreal=-W=Pe(V2-V1)Becausewedonotknowwhethertheprocessisreversibleornot，wedesignanisothermalreversibleprocesswiththesameinitialstat