锂电池自放电Self-discharge causes.ppt

Causesofself-dischargeBrianWayDecember12,2007

DendritescausedbymetalcontaminationincathodeThistypeisresponsibleformostself-dischargingcellsMetaldissolvesfromcathode,platesonanodeandgrowsdendritethroughseparatorSeeexampleonnextpageCausesofSelf-discharge

Example:FecontaminationincathodeFeAnode1)Fe2++2e-→Fe2)yLixC6?yLix-2/yC6+2Li++2e-1.Unchargedcell:Feparticleincathode3.Self-dischargingcell:Fedendritegrowsthroughseparator,touchescathode Fe↓Fe2+↓FeLi↑Li+↑LiCathode1)Fe→Fe2++2e-2)yLi1-xCoO2+2Li++2e-?yLi1-x+2/yCoO22.Chargedcell:Fepa