（9页PPT）假设3含时方程.pptVIP

Postulate3:

Thewe-functionofasystemevolvesintimeaccordingtothetime-dependentSchr?dingerequation

Assumption3:Thewe-functionofasystemevolvesintimeaccordingtothetime-dependentSchr?dingerequation-IngeneraltheHamiltonianHisnotafunctionoft,sowecanapplythemethodofseparationofvariables.

Time-independentSchr?dinger’sEquatione.g.Hatom

TheSchr?dinger’sEquationisaneigenvalueequation.I.TheeigenvalueofaHermitianoperatorisarealnumber.Proof:QuantummechanicaloperatorshetoherealeigenvaluesInanymeasurementoftheobservableassoc