还原剂红铝的应用.pptxVIP

还原剂红铝旳应用

SodiumBis(2-methoxyethoxy)aluminum

HydrideSomepracticaladvantagesofRed-AlarethatitdoesnotignitewhenexposedtomoistairorO2,hasgreatersolubilityinaromaticsolventsandethers,andreactionscanbecarriedoutathighertemperatures(upto200?C).AlternateName:SMEAH,Red-Al,Vitride.

1.ReductionofAlkenesandAlkynes

2.ReductiveRingOpeningofEpoxides

3.ReductionofCarboxylicAcidsandDerivatives

4.ReductionofKetonesandofAldehydes

5.Reductionofα,β-UnsaturatedCompounds

6.Nitrogen,SulfurandPhosphorusCompounds

7.Halides

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