（共17页PPT）高分子链的远程结构分子构象.pptVIP

IntroductiontoPolymerPhysicsLiWenboCollegeofMaterialsScienceandTechnologySouthChinaUniversityofTechnology

1.3.2.ConformationsofpolymerchainTheconformationsofamoleculearedefinedasdistinctspatialpositionsadoptedbyatomsorgroupsthroughrotationaroundsinglebondsorchangeintherelativepositionsofagivenunit(forexample,aring)joinedbyseveralsinglebonds.

Fortheethane(CH3-CH3)060o120o180o-60o-120o-180ou(j)jDe

TTTT…GGGG…(TG)(TG)(TG)(TGTG′)(TGTG′)(TG)2(TG′)2(T3G)(T3G′)(TTG)4(T2G2)2G：右旋傍式G′：左旋傍式

TGTG…