第四章 比共价键弱的键.pptVIP

4.1 分子间作用力 （范德华力） 氢 键 It complexes with Li+ and Na+, but not K+, Mg2+, or Ca2+. n = 5 It bonds simple cations such as Na+, K+, and Ca2+. Chromogenic Indoaniline Armed-Calix[4]azacrowns J. Org. Chem., 67 (18), 6514 -6518, 2002. Synthesis and Characterization of a Disulfide-Linked C5-Symmetric [5]Carceplex J. Am. Chem. Soc., 124 (1), 16 -17, 2002. Figure 3 Top view of [5]carceplex 7·(DMF)2 as predicted by MM2 calculations. The entrapped DMFs are predicted to be perpendicular to the C5 symmetry axis of 7. Water-Stabilized Cavitands J. Am. Chem. Soc., 124 (12),2854 -2855, 2002. Figure