催化裂化汽油脱硫技术.pdfVIP

化学通报 2006 年 第69 卷 20060422003 w099 催化裂化汽油脱硫技术 陈兰菊1,2 郭绍辉1* 赵地顺2 1 2 ( 石油大学(北京)重质油加工国家重点实验室 北京 100022 河北科技大学化学与制药工程学院 石家庄 050018) 摘 要 由于油品燃烧形成的硫的含氧化合物对环境的严重影响，世界各国对油品中硫含量的要求 越来越严格。为达到油品中硫含量的新标准，脱硫技术的发展越来越受到人们的重视。本文从催化裂化汽 油原料加氢预处理脱硫、加氢脱硫、吸附脱硫、氧化脱硫、催化裂化脱硫、溶剂萃取脱硫和生物脱硫等七 个方面对国内外的各种脱硫技术研究及进展进行了综述和分析。 关键词 催化裂化 汽油 脱硫 Research on Desulfurization Technology of Catalytic Cracking Gasoline Chen Lanju1,2, Guo Shaohui1*, Zhao Dishun2 1 2 ( State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249; College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018) Abstract Due to the dramatic environmental impact of sulfur oxides from oil combustion, sulfur content specifications in oils are becoming more and more stringent worldwide. To meet the new regulation mandates, desulfurization technology will be attached importance to people. The desulfurization technologies and developments of flow catalytic cracking gasoline were reviewed and analyzed from these ways of hydrogen ation material, hydrogen desulfurization, adsorption desulfurization, oxidation desulfurization, catalytic cracking desulfurization, solvent extraction desulfurization and biology desulfurization in this paper. Key words Flow catalytic cracking, Gasoline, Desulfurization 随着人民生活水平的提高，对环保的要求日趋严格，生产清洁燃料是全球炼油工业发展的总趋 势。空气污染的主要因素之一是汽车尾气中的SO ，它主要来自于催化裂化(FCC)汽油中的有机硫化 x 物。国外汽油一般约34%来自FCC 流程，我国约80%的汽油来自FCC 流程，而汽油中90% 以上的 硫来自FCC 汽油，这使