[北京科技大学分离分析化学]2复杂物质分离-第二章.pptVIP

第一章 试样的采取和制备  PREPARING SAMPLES FOR ANALYSIS §1-1 Sampling §1-2 Preparation of the Sample §1-3 Decomposing and Dissolving the Sample §1-1 试样的采取 SAMPLING Weight of Sample Sampling Unit Sampling Mode Sampling Principle Application §1-2 试样的处理 PREPARATION OF THE SAMPLE Crushing and Grinding sifting mixing dividing Moisture in Samples §1-3 试样的分解和溶解DECOMPOSING AND  DISSOLVING THE SAMPLE Dissolution Fusion Sintering Decomposition of Organic Compounds Modern Decomposing Techniques 第二章 沉淀分离法PRECIPITATION SEPARATION Reference: 1. 《近代分离方法导论》,方宾,阚显文;安徽人民出版社,2006.8. 2. 《化学分离富集方法及应用》, 《化学分离富集方法及应用》编委会,中南工业大学出版社,1996 3. 《分析化学中的分离方法》,王应玮,梁树权编著,科学出版社,1998 4. 《分离过程化学》,陆九芳等,清华大学出版社,1990 第二章 沉淀分离法PRECIPITATION SEPARATION Reference: 5. 《生化分离技术》,田亚平等;化学工业出版社,2006.8. 6. 《Analytical Chemistry for Technicians》, John Kenkel, Lewis Publishers,Inc.,1988 7. 《Quantitative Analysis》,R.A.DAYJR,A.L.UNDERWOOD,six edition,Prentice Hall,Englewood Cliffs,New Jersey,1991 第二章 沉淀分离法PRECIPITATION SEPARATION §2-1 概述 Summarization §2-2 直接沉淀法 Direct Precipitation Method §2-3 均相沉淀法 Precipitation from Homogeneous Solution §2-4 共沉淀富集法 Coprecipitation Enrichment §2-5 沉淀分离法进展 development of Precipitation [23] §2-1 概述 SUMMARIZATION 沉淀分离法的特点[9] Characteristics of Precipitation Separation 沉淀分离依据及应用条件[9] Ground and Conditions for the Application of Precipitation Separation 沉淀形成机理 Mechanism of Precipitation [10] 沉淀分离法的分类及应用[9] Classification and application of Precipitation Separation 沉淀分离法的特点CHARACTERISTICS OF PRECIPITATION SEPARATION [9] 优点：Advantage 设备简单 应用广泛 缺点：Disadvantage 误差大 选择性差 沉淀分离繁琐费时 沉淀分离依据及应用条件 GROUND AND CONDITIONS FOR THE APPLICATION OF PRECIPITATION SEPARATION [9] Ksp,M/Ksp,N≤ 10-3 形成机理 MECHANISM OF PRECIPITATION [10] 沉淀平衡 precipitation equilibrium mMn+ + nAm- → MmAn Ksp =[M]m[A]n 当[M]m[A]n ＞ Ksp 时, 应有沉淀生成. 形成机理MECHANISM OF PRECIPITATION [10] 2)过饱和度与相