生物质锅炉过热器高温腐蚀研究.pdf

23 7 Vol2 3 No7 20 10 7 GUA GDO GELECTRIC POWER Jul20 10 1 2 印佳敏 , 吴占松 ( 1 广东省电力设计研究院, 广东 广州5106 63 ; 2 清华大学, 北京 10 00 84) : 通过在 1 台实际运行的生物质锅炉过 器管道处进行现场挂片试验, 对常用过 器管道材料12 Cr1MoVG 和TP316L 进行了腐蚀试验研究; 利用扫描电镜SEMEDSX 荧光光谱仪和X 射线衍射对腐蚀产物和过 器表 面积灰的微观形貌元素含量和组分进行分析试验表明, 过 器管道上积灰比较严重, 并且从管道的迎风面 到背风面, 积灰层的厚度逐渐增加; 12 Cr1MoVG 的表层灰渣下有叶片状组织生成, 而TP316L 表层灰渣中出现 了KCl 晶体; 灰渣层的主要成分为K SO 2 4 : 生物质锅炉; 过 器; 高温腐蚀; 积灰 : TK2 249 : A : 100 72 90X(2 010)0 70 03 104 Investigation on Hightemperature Corrosion of Superheaters in Biomass Boiler 1 2 YIN Jiamin , W Zhansong ( 1 Guangdong Electric Power Design Inst, Guangzhou, Guangdong 510663, China; 2 Tsinghua niv, Beijing 100 084, China) Abstract: Corrosion behavior of 12 Cr1MoVG and TP3 16L were investigated by coupon test carried out at superheaters of a biomass boiler The metal species were analyzed by scanning electron microscope and energy dispersive spectrometer (SEM EDS) , Xray fluorescence spectrometer and Xray diffractometer to detect the appearance, the element contents and the composition of corrosion productsand superheater surface deposition The results showed that massive deposition was formed on the surface of the metal species The thickness of deposition was increased from windward to leeward Sheetlike framework was formed under the slag of 12 Cr1MoVG while KCl appeared in the slag of TP316L The composition of slag was mainly K SO 2 4 Key words: biomass boiler; superheater; hightemperature corrosion; ash deposition , Cl , , , , HCl