干法纺丝制备BTCA改性PEG_PVA相变储能纤维的结构与性能.docVIP

  干法纺丝制备 BTCA 改性 PEG/PVA 相变储 能纤维的结构与性能# 李佳佳，许维星，罗森，徐建军，叶光斗，姜猛进** 5 10 15 20 25 30 35 40 （四川大学高分子科学与工程学院，高分子材料与工程国家重点实验室，成都 610065） 摘要：将相变材料聚乙二醇（PEG）与聚乙烯醇（PVA）溶液混合，加入不同含量的丁烷四 羧酸（BTCA）作为交联改性剂配制一系列纺丝原液，采用干法纺丝制得相变储能纤维。研 究了 BTCA 含量、热处理条件对交联程度的影响，并通过傅里叶红外光谱仪、扫描电子显 微镜和差示扫描量热仪对纤维的结构、形态以及储能性能进行了分析。结果表明：由干法纺 丝制备出了 BTCA 改性 PEG/PVA 相变储能纤维；热处理条件为 180/12min 或 190/10min 时，纤维可达到良好的交联效果；纤维的交联程度随 BTCA 含量的增加呈上升趋势，BTCA 含量接近 3wt.%时趋于平缓；改性后的纤维内 PEG 以独立微相区形式存在，复合纤维经沸 水煮后，相变焓保留率高达 80%，具有良好的储能性。 关键词：干法纺丝；丁烷四羧酸；改性；聚乙烯醇；聚乙二醇；储能纤维 中图分类号：TQ342+.4 Structures and properties of BTCA modified energy storage PEG/PVA fiber prepared through dry spinning LI Jiajia, XU Weixing, LUO Sen, XU Jianjun, YE Guangdou, JIANG Mengjin (College of Polymer Science and Engineering, State Key Laboratory of Polymer Material and Engineering, Sichuan University, ChengDu 610065) Abstract: Butane tetracarboxylic acid (BTCA) as a cross-linking modifier was added to the blend solution of polyethylene glycol (PEG) and polyvinyl alcohol (PVA) to prepare the spinning solution. Though dry spinning, a serious of energy storage fibers with different contents of BTCA were obtained. The influence of BTCA content and heat treatment conditions on cross-linking degree was investigated. Structure and morphology of the fibers and their energy storage performance were analyzed by FTIR, SEM and DSC respectively. Results show that BTCA modified PEG/PVA fibers were successfully achieved according to the principle of dry spinning method. The gel content could reach an ideal effect under the heat treatment of 180℃/12min or 190℃/10min. The gel content of the fibers went up as the BTCA content rose and then leveled off when the BTCA content reached 3wt.%,. PEG existed in the fiber as many independent micro-phase regions, which endowed the fiber with good energy storage performance with the retention rate as high as 80% even after being boiled in water. Keywords: dry spinning; butane tetracarboxylic acid; modify; polyvinyl alcohol; polyethy