PEG-壳聚糖相变材料的研制.pdfVIP

PEG/壳聚糖相变材料的研制 摘 要 将 PEG 和壳聚糖 （Chitosan ）溶液共混，可得到一种具有固固相变性能的储能 材料。该复合物实际上是 PEG 与壳聚糖之间的物理混合物，混合物中 PEG 的结晶 结构并没有发生变化，但是 PEG 的端羟基与壳聚糖分子链上的侧氨基之间形成了 强烈的氢键作用。PEG 与 Chitosan 间存在的较强的分子间氢键，束缚和限制了复 合物中 PEG 熔融态的平动自由，致使复合物在高温态下表现出固体化行为。并用 DSC 具体研究了PEG 的百分含量及PEG 的分子量对共混材料的相变温度和相变焓 的影响。研究结果表明，通过改变 PEG 的百分含量与PEG 的分子量，可以得到不 同相变焓和不同相变温度的相变材料。分析表明，此共混物具有较好的热稳定性。 聚乙二醇与壳聚糖共混的相变材料表现固固相变材料将作为一种新型的热储能和 温控相变材料。 关键词：PEG，壳聚糖，共混，相变材料 I PEG/壳聚糖相变材料的研制 Abstract New kinds of solid-solid phase change materials(PCMs) have prepared.In these materials,PEG （polyethylene glycol ）had been blent with chitosan from a mixed solution.The composite is a physical mixture in fact.In this composite, the crystallographic structure of polyethylene glycol had not been changed.The ending hydroxyl of polyethylene and the amido in the molecule of chitosan had formed intense hydrogenolybonds.There is strong interaction between PEG and chitosan based upon intermolecular hydrogenbonds,which restricts the freedom of the transitional motion of the PEG within the composite at its melting point and makes it exhibit solid fication phse behabior.In this paper,the effects of molecular weight and weight percentage of PEG in composition on energy storage properties were discussed by DSC.The results showed that PCMs with different latent heat,defferent phase transition temperatre and different mechanical strength can be obtained by means of modifying the molecular weight and weight percentage of PEG.It had been indicated that