PET及PVC的热重分析的研究.pdfVIP

PVC 及 PET 的热重分析的研究 摘 要 热重分析法(TG)是应用热天平在程序控制温度，测量物质质量与温度关系的 一种热分析技术，具有操作简便、准确度高、灵敏快速以及试样微量化。本次试 验的研究对象是聚对苯二甲酸乙二酯(聚酯PET)和聚氯乙烯(PVC) 。本文通过热重 分析研究了PVC和PET在不同升温速率，不同氮气流量以及不同样品质量下的热 解行为。其中PVC 热解过程可分为 3 个阶段，250-350 ℃为第一失重阶段、 350-450℃为稳定阶段、450-600 ℃为第二失重阶段。PET热解过程可分为 2 个阶 段，400-500 ℃为第一失重阶段 500-600 ℃为第二失重阶段。升温速率对两者热 解有较显著的影响,随升温速率的增加,T 、T （T -失重的起始温度T -失重的终 b f b f 止温度），氮气流量和样品质量的改变对T 、T 影响不大，主要对最终失重百分 b f 比V 产生影响。根据实验结果,求出了各个反应方程的活化能，该模型与实验结 f 果符合较好，能为PVC和PET 的热解处理装置的设计或运行提供帮助。 关键词 聚对苯二甲酸乙二酯，聚氯乙烯，热解动力学， 热重分析法 I PVC 及 PET 的热重分析的研究 ABSTRACT Thermal decomposition of PVC resin has been examined by thermogravimetric analysis. The results of the pyrolytic experiment indicate that the degradation process can be divided into three stages,the first weight loss stage is from 250°C to 350°C, thermally stable stage is from 350°C to 450°C and the second weight loss stage is from 450°C to 600°C. The thermal degradation behaviors of PVC resin are affected greatly by heating rate.T and T increase with the increasing heating rate, while the b f ratio of weight loss at each weight loss stage changes little. The results of the PET experiment indicate that the degradation process can be divided into two stages first weight is from 400°C to 500°C ，the second weight loss stage is from 500°C to 600°C 。 According to the experimental result, before extracting each response equation activation energy, the factor and the order of reaction. This model and the experimental result tallies well, can be