化学改性石墨毡材料在电芬顿体系中高效产过氧化氢的研究.doc

  化学改性石墨毡材料在电芬顿体系中高效 产过氧化氢的研究 周蕾，胡忠心，金涛，李运林，周明华** 5 10 15 20 25 30 （南开大学环境科学与工程学院，天津 300071） 摘要：电芬顿方法在难降解有机污染物的处理方面显示了较好的应用前景，但高效产过氧化 氢阴极仍是提高系统效率的关键。为此，本文采用水合肼-乙醇溶液对石墨毡阴极材料进行 化学掺氮改性，在 SEM、CV 等表征基础上，讨论了不同水合肼浓度对过氧化氢产量和效率 的影响。研究发现：在水合肼浓度为 10%的乙醇溶液中，经过改性的石墨毡材料在偏压为 -0.65V（vs. SCE）条件下具有最佳的过氧化氢产量，反应 2h 达到 176.8 mg/L，约为改性处 理前的 2.6 倍。通过对对硝基苯酚的电催化降解发现，在相同条件下 NCF-10%的 TOC 去除 率为 73.7%，较改性前提高了 21.5%。此方法为提升电芬顿效率、促进环境应用提供了新途 径。 关键词：石墨毡；水合肼；过氧化氢；电芬顿；对硝基苯酚 中图分类号：X505 Chemical modified graphite felts for highly efficient electrocatalytic generation of hydrogen peroxide in Electro-Fenton system Zhou Lei, Hu Zhongxin, Jin Tao, Li Yunlin, Zhou Minghua (Institute of Environmental Science and Engineering, Nankai University, TianJin 300071) Abstract: Electro-Fenton process (EF) is a promising method for degradation of refractory pollutants in aquatic environment. The suitable cathode which produces hydrogen peroxide by oxygen reduction still plays a key role in the efficiency improvement of the EF. In this study, hydrazine hydrate-ethanol system was used to modify graphite felts, and the influence of the concentration of hydrazine hydrate on the production and efficiency of hydrogen peroxide was discussed based on the SEM and CV characterizations. When the concentration of hydrazine hydrate was 10%, the obtained cathode (NCF-10%) had the highest activity under -0.65V (vs. SCE), up to 176.8 mg/L hydrogen peroxide was produced in 2 h, which was about 2.6 times of that before modification. The mineralization of p-nitrophenol in EF system was also investigated, and the TOC removal of NCF-10% sample was 73.7%, 21.5% higher than the undoping one, under the same conditions. This method could provide a new approach to enhance the efficiency and promote the environmental applications of EF. Keywords: Graphite felts; Hydrazine hydrate; Hydrogen peroxide; Electro-Fenton; p-Nitrophenol 35 0 引言 电芬顿（Electro-Fenton, EF）的研究始于 20 世纪 80 年代，是近年来发展的一种新型的 水处理电化学高级氧化技术，被广泛应用于难降解污染物的治理研究[1]。与传统的化学芬顿 法相比，电芬顿