Mg-Zn-Nd准晶合金显微组织和电化学性能研究.docVIP

  Mg-Zn-Nd 准晶合金显微组织和电化学性能 研究# 张金山，徐继东* 5 10 15 20 25 30 35 40 （太原理工大学材料科学与工程学院，太原 030024） 摘要：采用常规铸造的方法，制备出含有准晶相成分的 Mg70.8Zn28Nd1.2 合金，采用 TEM 和 XRD 的方法对制备出的准晶合金进行微观组织分析。经过 600k, 48 小时的热处理后，合 金的准晶相的结构和形态都没有发生变化。基体 Mg7Zn3 相转变成蜂窝状共晶 Mg+MgZn 相， 用电化学的方法测试合金的储氢性能。电化学实验结果表明：当准晶相处在 Mg7Zn3 基体相 包围之中时，铸态合金有很小的电化学容量。经过热处理后，由于合金中 Mg7Zn3 基体相转 变为 Mg+MgZn 共晶相。其最大放电容量变为 36mAh/g。由于本合金中准晶相只有 45%左右， 而其他的相在本实验条件下又无法与 H 发生反应，这些结果表明准晶相具有良好的电化学 储氢能力。 关键词：镁合金；准晶；电化学；储氢材料 中图分类号：GT292 Study on the Microstructure and Electrochemical Hydrogen Storage Properties of Mg-Zn-Nd Quasicrystal Alloy ZHANG Jinshan, XU Jidong (College of Material Science and Engineering, Taiyuan University of Techonology, Taiyuan 030024) Abstract: Mg70.8Zn28Nd1.2 alloy containing icosahedral quasicrystal phase was prepared under conventional casting conditions. The microstructures and phases structure of quasicrystal alloy were investigated by means of SEM and XRD. There is not change in morphology and structure for icosahedral phase after being annealed at 600k for 48h. The Mg7Zn3 matrix phase transformed into a kind of honeycombed eutectic organization which is Mg and MgZn eutectic phase.The hydrogen storage capacity of Mg70.8Zn28Nd1.2 quasicrystal alloy was investigated by electrochemical testing. The result shows that the as-cast alloy has low discharge capacity when quasicrystal phase is enclosed by Mg7Zn3 phase. After the heat treatment, Mg7Zn3 phase changed into Mg and MgZn phase, and the maximum discharge capacity was 36mA/g. Because the ratio of the volume fraction of icosahedral phase is only about 45%, and the other phases can’t react with hydrogen, the icosahedral quasicrystal phase has high electrochemical hydrogen storage capacity. Key words: magnesium alloy；Quasicrystal； Electrochemical magnesium alloy； Hydrogen Storage Material 0 引言 准晶体是一种新的具有旋转对称结构和原子长程有序的结构种类[1]。自从准晶这一结构 被发现以来，准晶的制备、性能及应用研究也一直受到人们普遍的关注。罗治平在 1993 年 首次在常规常温下制备出含有稀土元素的镁基准晶相以后[2]，人们对于 Mg-Zn-ER 准晶的显 微组织和力学性能做了大量研究。但目前对于镁基准晶的研究主要集中在了结构材料的