卧龙湖煤矿岩浆侵入区煤中稀土元素的地球化学特征.docVIP

  卧龙湖煤矿岩浆侵入区煤中稀土元素的地 球化学特征# 姜萌萌，刘桂建，吴斌，郑刘根** 5 10 （中国科学技术大学地球和空间科学学院，中国科学院壳幔物质和环境重点实验室，安徽合 肥市 230026） 摘要：以淮北卧龙湖煤矿包含岩浆岩、煤层的剖面为研究对象，通过对岩浆岩、煤岩混合带、 高变质煤样品采集，结合逐级化学提取实验，采用等离子体质谱（ICP-MS）对原煤样、岩 浆岩样、煤灰分、以及煤和岩浆岩逐级提取实验中各种提取物的稀土元素进行了测试，系统 深入地研究了稀土元素的含量特征、分布模式以及赋存状态。研究结果表明，岩浆岩在侵入 过程中与煤层间发生一定的物质交换作用，岩样与煤样中的稀土元素分布模式相差较大，逐 级化学提取实验结果表明煤和岩浆岩中稀土元素都是以硅酸盐结合态占主导，但煤中稀土元 素主要来源于陆源碎屑的供给。 15 关键词：岩浆岩 煤 稀土元素 地球化学 中图分类号：P594；P618 Geochemistry of Rare Earth Elements (REEs) in Coal from magmatic intrusion area from Wolonghu Coal Mine 20 25 30 Jiang mengmeng, Liu Guijian, WU Bin, Zheng Liugeng (CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026) Abstract: Magmatic rock samples and adjacent coal samples were collected from a vertical section in the Wolonghu Coal Mine, Huaibei. Combine with the step by step extraction experiment ，the abundances of rare earth elements (REEs) in samples and coal-ash were determined by inductively couple-plasma mass spectrometry (ICP-MS). The occurrences of REEs were studied using Sequential Chemical Extraction Experiment (SCEE) in different extraction liquids and conditions. The characterizations of the concentration, distribution patterns and the occurrence of REEs are analyzed. The results show that exchange of material between the magma and the coals occurred as the magmatic intrusion process. Due to the superimposition of coal-forming microenvironment and magmatic intrusion, the distribution patterns of magma and coals are different. The result of SCEE shows that REEs mainly distribute in sialic state, and the source of REEs is terrigenous matters. Key words: magma, Coal, rare earth elements (REEs), Geochemistry 35 0 引言 稀土元素具有化学性质稳定，均一化程度高，不易受变质作用影响的特性，研究表明： 煤中稀土元素的含量特征、分布模式、赋存状态以及地球化学参数可以示踪煤的地质成因， 揭示源区供给，从而区分不同的物源环境；同时根据煤中稀土元素的含量变化可以为烃源岩 40 的演化、沉积环境、后生地质构造作用以及岩浆岩侵入等提供相关的证据，因而煤中稀土元 素受到国内外学者的广泛关注[1-8]。由于成煤植物对稀土元素特征的影响十分有限，所以煤 基金项目：国家自然科学基金（40873