0.8mm超薄型石墨双极板一次热模压成型工艺研发.pdfVIP

·32 · 材料导报网刊 2012 年 6 月第 7 卷第 2 期 0.8mm 超薄型石墨双极板一次热模压成型工艺研发* 吴 祺, 唐普洪 （嘉兴职业技术学院，嘉兴 314036 ） 摘要 为降低质子交换膜燃料电池(PEMFC)的生产成本，减轻燃料电池自重，避免石墨双极板机加工二次工序的不足， 以酚醛树脂和石墨为骨料，采用一次热模压成型工艺制备了 0.8mm 石墨双极板。结果表明，经模具改进设计和石墨表面包 裹两道工艺后，与 1.6mm 双极板性能相比，0.8mm 石墨双极板压综合性能有所提高。其压缩强度大于 110 MPa，弯曲强度 -6 大于 38 MPa ，体积电阻率小于 55 ×10 Ω •m ，自重减轻60%左右，制造成本减少 53%。所组装的单电池能满足燃料电池苛 刻的工作条件及性能要求。在模拟 PEMFC 环境中，用伏安法测量石墨双极板与碳纸之间的接触电阻显示，石墨双极板电流 2 密度低于 16μA/cm ，电流没有出现明显的波动。 关键词 质子交换膜燃料电池 石墨双极板 模具 表面改性 Development of 0.8mm Bipolar Plate of Proton Exchange Membrane Full Cell in a Hot Molding Process WU Qi, TANG Puhong (Jiaxing Vocational Technical College, Jiaxing 314036) Abstract To reduce the proton exchange membrane fuel cell (PEMFC) production costs, weight and secondary machining, 0.8mm graphite bipolar plates was prepared by using phenolic resin and graphite as the aggregate in a hot molding process. Results showed that, 0.8mm graphite bipolar plate was superior to the 1.6mm ones after an improvement of mold design and surface packaging of graphite. Correspondingly, the in compression strength, bending strength and volume resistance of 0.8mm graphite bipolar plate reached 110MPa, 38MPa and 55×10-6Ω•m, the weight and manufacturing costs reduced by 60% and 53% ,respectively. These bipolar plates can meet the harsh working conditions and performance requirements after it being assembled to fuel cell. Voltammetry measurement of contact resistance between graphite bipolar pl