高分散Pd基电催化剂：交替微波和回流法制备及对甲醇的催化氧化性能.pdfVIP

高分散Pd 基电催化剂：交替微波和回流法制备及对甲醇的催化氧化性能/谭 瑶等 ·35 · 高分散 Pd 基电催化剂：交替微波和回流法制备及 对甲醇的催化氧化性能 1 1 1 2 2 谭 瑶 ，雷 燕 ，何立平 ，廖明佳 ，魏子栋 （1 重庆三峡学院化学与环境工程学院，重庆 404000 ；2 重庆大学化学化工学院，重庆 400044 ） 摘要 以多壁碳纳米管 （MWCNT ）为载体，利用交替微波加回流加热法制备了担载型 Pd 基电催化剂，并表征了其 微观形貌及电化学性能。通过循环伏安曲线实验证明，在碱性溶液中，Pd-Ni/CNTs 比纯Pd/CNTs 具有更高的甲醇氧化性能。 甲醇氧化的起始电位负移了20mV 左右，氧化峰的电流密度也比Pd/CNTs 高出 11mA 左右。Pd-Ni/CNTs 的高催化活性不仅 与其高活性表面积有关，而且也和 Ni 之间的协同作用有关。 关键词 甲醇氧化 碳纳米管 Pd 基电催化剂 Highly Dispersed Pd-based Electrocatalysts: Preparation by Pulse-Microwave and Reflux and Catalytic Performance toward Electro-oxidation of Methanol 1 1 1 2 2 TAN Yao , LEI Yan , HE Liping , LIAO Mingjia , WEI Zidong ( 1 School of Chemistry and Environmental Engineering, Chongqing Three Gorges University, Chongqing 404000; 2 School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044) Abstract Pd nanoparticles were supported on multi-walled carbon nanotubes (MWCNTs) by intermittent microwave heating (IMH) and reflux technique. The morphologies and electrochemical properties of the electrocatalysts were characterized. The cyclic voltammetric experiments indicate that Pd-Ni/CNTs electrocatalyst exhibits a better performance for methanol oxidation than Pd/CNTs in alkaline media. A negative shift over 20mV of the onset potential for methanol oxidation was found on Pd-Ni/CNTs compared to that on Pd/CNTs. Current density of oxidation peak is 11mA over the Pd/CNT. The results indicated that the enhancement in the activity for methanol oxidation on Pd-Ni/CNTs was due to not only the increase in the active surface area but a