2-吡嗪甲酸钐配合物的合成表征初稿论文.doc

摘 要 本文以2-吡嗪甲酸(简写Hpya)和SmCl3·6H2O反应得到2-吡嗪甲酸钐配合物{[Sm(pya)3(H2O)](H2O)3}n，并用X-射线单晶结构分析进行表征。X-射线单晶结构分析表明：2-吡嗪羧酸钐配合物属于正交晶系，空间群为Pbcn。相关晶胞参数：a=16.154(3)?，b=12.357(3)?，c=20.525(4)?，a=β=γ=90o，V=4097.1。配合物中钐原子被三个氮原子和六个氧原子包围，形成一个畸变的三帽三棱柱9配位化合物，其中只有一个配位氧原子来自水分子而其他配位氧原子则由2-吡嗪羧酸配体提供。通过相邻配体氢键及范德华力作用形成三维超分子网状结构。 关键词：2-吡嗪羧酸；钐配合物；氢键；晶体结构；表征 Abstract The coordination compound {[Sm(pya)3(H2O)](H2O)3}n was obtained by reaction of 2-pyrazinecarboxylic Acid (Hpya) with SmCl3·6H2O,and it was characterized by X-ray diffraction single-crystal analyses indicate that the compound crystallize in cubiccrystal system,space group Pbcn, crystal data: a=16.154(3)?, b=12.357(3)?, c=20.525(4)?, a=β=γ=90o, V=4097.1. The complex of Sm(III) atom surrounded by three N atoms and two oxygen atoms form a slightly distorted tricapped trigonal prism with nine atoms coordination, in which one ligand oxygen atom from a water molecule with other N atoms by 2 –pyrazine carboxylic acid ligands provided. Moreover, the adjacent tow-dimensional polymeric layers of the three complex can be assembled into a three-dimensional framework via Hydrogen bonds. Key words: 2-pyrazinecarboxylic Acid; Samarium complex; Hydrogen bonds; crystal structure; characterization 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc262984282 摘 要 PAGEREF _Toc262984282 \h I HYPERLINK \l _Toc262984283 前 言 PAGEREF _Toc262984283 \h 1 HYPERLINK \l _Toc262984284 文献综述 PAGEREF _Toc262984284 \h 2 HYPERLINK \l _Toc262984285 1.1 配合物的国内外研究现状 PAGEREF _Toc262984285 \h 2 HYPERLINK \l _Toc262984286 1.1.1 国外配合物研究现状 PAGEREF _Toc262984286 \h 2 HYPERLINK \l _Toc262984287 1.1.2 国内配合物研究现状 PAGEREF _Toc262984287 \h 2 HYPERLINK \l _Toc262984288 1.2 配合物的合成方法 PAGEREF _Toc262984288 \h 3 HYPERLINK \l _Toc262984289 1.2.1 简单的合成方法 PAGEREF _Toc262984289 \h 3 HYPERLINK \l _Toc262984290 1.2.2 特殊合成方法 PAGEREF _Toc262984290 \h 3 HYPERLINK \l _Toc262984291 1.3 吡嗪羧酸稀土配合物的研究进展 PAGEREF _Toc262984291 \h 4 HYPERLINK \l _Toc262984292 1.3.1 稀土元素简介 PAGEREF _Toc262984292 \h 4